The asymmetric intramolecular Heck reaction in natural product total synthesis AB Dounay, LE Overman Chemical reviews 103 (8), 2945-2964, 2003 | 1793 | 2003 |
Catalytic enantioselective synthesis of quaternary carbon stereocentres KW Quasdorf, LE Overman Nature 516 (7530), 181-191, 2014 | 945 | 2014 |
Catalytic asymmetric synthesis of all-carbon quaternary stereocenters CJ Douglas, LE Overman Proceedings of the National Academy of Sciences 101 (15), 5363-5367, 2004 | 903 | 2004 |
" Artificial enzyme" combining a metal catalytic group and a hydrophobic binding cavity R Breslow, LE Overman Journal of the American Chemical Society 92 (4), 1075-1077, 1970 | 482 | 1970 |
Total synthesis of complex cyclotryptamine alkaloids: stereocontrolled construction of quaternary carbon stereocenters A Steven, LE Overman Angewandte Chemie International Edition 46 (29), 5488-5508, 2007 | 462 | 2007 |
A general method for the synthesis of amines by the rearrangement of allylic trichloroacetimidates. 1, 3 Transposition of alcohol and amine functions LE Overman Journal of the American Chemical Society 98 (10), 2901-2910, 1976 | 448 | 1976 |
Mercury(II)‐ and Palladium(II)‐Catalyzed [3,3]‐Sigmatropic Rearrangements [New Synthetic Methods (46)] LE Overman Angewandte Chemie International Edition in English 23 (8), 579-586, 1984 | 421 | 1984 |
Contiguous stereogenic quaternary carbons: A daunting challenge in natural products synthesis EA Peterson, LE Overman Proceedings of the National Academy of Sciences 101 (33), 11943-11948, 2004 | 396 | 2004 |
Vinylsilane-and alkynylsilane-terminated cyclization reactions TA Blumenkopf, LE Overman Chemical Reviews 86 (5), 857-873, 1986 | 383 | 1986 |
Oxalates as activating groups for alcohols in visible light photoredox catalysis: formation of quaternary centers by redox-neutral fragment coupling CC Nawrat, CR Jamison, Y Slutskyy, DWC MacMillan, LE Overman Journal of the American Chemical Society 137 (35), 11270-11273, 2015 | 374 | 2015 |
Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Investigations of Intramolecular Heck Reactions of (E)-α,β-Unsaturated 2-Haloanilides … A Ashimori, B Bachand, LE Overman, DJ Poon Journal of the American Chemical Society 120 (26), 6477-6487, 1998 | 339 | 1998 |
Intramolecular alkene arylations for rapid assembly of polycyclic systems containing quaternary centers. A new synthesis of spirooxindoles and other fused and bridged ring systems MM Abelman, T Oh, LE Overman The Journal of Organic Chemistry 52 (18), 4130-4133, 1987 | 332 | 1987 |
Allylic and propargylic imidic esters in organic synthesis LE Overman Accounts of Chemical Research 13 (7), 218-224, 1980 | 332 | 1980 |
Strategic use of visible-light photoredox catalysis in natural product synthesis SP Pitre, LE Overman Chemical Reviews 122 (2), 1717-1751, 2021 | 325 | 2021 |
Synthetic strategies toward natural products containing contiguous stereogenic quaternary carbon atoms M Bueschleb, S Dorich, S Hanessian, D Tao, KB Schenthal, LE Overman Angewandte Chemie International Edition 55 (13), 4156-4186, 2016 | 317 | 2016 |
Catalytic asymmetric rearrangement of allylic trichloroacetimidates. A practical method for preparing allylic amines and congeners of high enantiomeric purity CE Anderson, LE Overman Journal of the American Chemical Society 125 (41), 12412-12413, 2003 | 311 | 2003 |
Thermal and mercuric ion catalyzed [3, 3]-sigmatropic rearrangement of allylic trichloroacetimidates. 1, 3 Transposition of alcohol and amine functions LE Overman Journal of the American Chemical Society 96 (2), 597-599, 1974 | 311 | 1974 |
Direct Construction of Quaternary Carbons from Tertiary Alcohols via Photoredox-Catalyzed Fragmentation of tert-Alkyl N-Phthalimidoyl Oxalates GL Lackner, KW Quasdorf, LE Overman Journal of the American Chemical Society 135 (41), 15342-15345, 2013 | 308 | 2013 |
Asymmetric synthesis of either enantiomer of opium alkaloids and morphinans. Total synthesis of (-)-and (+)-dihydrocodeinone and (-)-and (+)-morphine CY Hong, N Kado, LE Overman Journal of the American Chemical Society 115 (23), 11028-11029, 1993 | 307 | 1993 |
Catalytic asymmetric synthesis of either enantiomer of the calabar alkaloids physostigmine and physovenine T Matsuura, LE Overman, DJ Poon Journal of the American Chemical Society 120 (26), 6500-6503, 1998 | 301 | 1998 |