A highly active catalyst for Pd-catalyzed amination reactions: cross-coupling reactions using aryl mesylates and the highly selective monoarylation of primary amines using aryl … BP Fors, DA Watson, MR Biscoe, SL Buchwald Journal of the American Chemical Society 130 (41), 13552-13554, 2008 | 634 | 2008 |
A new class of easily activated palladium precatalysts for facile C− N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides MR Biscoe, BP Fors, SL Buchwald Journal of the American Chemical Society 130 (21), 6686-6687, 2008 | 530 | 2008 |
Pd-catalyzed amidations of aryl chlorides using monodentate biaryl phosphine ligands: A kinetic, computational, and synthetic investigation T Ikawa, TE Barder, MR Biscoe, SL Buchwald Journal of the American Chemical Society 129 (43), 13001-13007, 2007 | 341 | 2007 |
Stereospecific Pd-catalyzed cross-coupling reactions of secondary alkylboron nucleophiles and aryl chlorides L Li, S Zhao, A Joshi-Pangu, M Diane, MR Biscoe Journal of the American Chemical Society 136 (40), 14027-14030, 2014 | 251 | 2014 |
Structural insights into active catalyst structures and oxidative addition to (biaryl) phosphine− palladium complexes via density functional theory and experimental studies TE Barder, MR Biscoe, SL Buchwald Organometallics 26 (9), 2183-2192, 2007 | 236 | 2007 |
Nickel-catalyzed Kumada cross-coupling reactions of tertiary alkylmagnesium halides and aryl bromides/triflates A Joshi-Pangu, CY Wang, MR Biscoe Journal of the American Chemical Society 133 (22), 8478-8481, 2011 | 196 | 2011 |
Enantiodivergent Pd-catalyzed C–C bond formation enabled through ligand parameterization S Zhao, T Gensch, B Murray, ZL Niemeyer, MS Sigman, MR Biscoe Science 362 (6415), 670-674, 2018 | 193 | 2018 |
Stereoretentive Pd-catalysed Stille cross-coupling reactions of secondary alkyl azastannatranes and aryl halides L Li, CY Wang, R Huang, MR Biscoe Nature chemistry 5 (7), 607-612, 2013 | 168 | 2013 |
Nickel-catalyzed Negishi cross-coupling reactions of secondary alkylzinc halides and aryl iodides A Joshi-Pangu, M Ganesh, MR Biscoe Organic letters 13 (5), 1218-1221, 2011 | 127 | 2011 |
Cross Coupling and Heck-Type Reactions 1 GA Molander, MR Biscoe, B Carboni, F Carreaux, WTT Chang, ... Thieme Verlag, 2013 | 124 | 2013 |
Electronic Effects on the Selectivity of Pd‐Catalyzed C N Bond‐Forming Reactions Using Biarylphosphine Ligands: The Competitive Roles of Amine Binding and Acidity MR Biscoe, TE Barder, SL Buchwald Angewandte Chemie International Edition 46 (38), 7232-7235, 2007 | 124 | 2007 |
Selective monoarylation of acetate esters and aryl methyl ketones using aryl chlorides MR Biscoe, SL Buchwald Organic letters 11 (8), 1773-1775, 2009 | 115 | 2009 |
Configurationally stable, enantioenriched organometallic nucleophiles in stereospecific Pd-catalyzed cross-coupling reactions: an alternative approach to asymmetric synthesis CY Wang, J Derosa, MR Biscoe Chemical science 6 (9), 5105-5113, 2015 | 99 | 2015 |
Palladium-catalyzed borylation of primary alkyl bromides A Joshi-Pangu, X Ma, M Diane, S Iqbal, RJ Kribs, R Huang, CY Wang, ... The Journal of organic chemistry 77 (15), 6629-6633, 2012 | 84 | 2012 |
Stereoselectivity in Pd-catalysed cross-coupling reactions of enantioenriched nucleophiles X Ma, B Murray, MR Biscoe Nature Reviews Chemistry 4 (11), 584-599, 2020 | 55 | 2020 |
Simple, efficient protocols for the Pd-catalyzed cross-coupling reaction of aryl chlorides and dimethylamine BK Lee, MR Biscoe, SL Buchwald Tetrahedron letters 50 (26), 3672-3674, 2009 | 55 | 2009 |
Oxaziridinium salts as hydrophobic epoxidation reagents: remarkable hydrophobically-directed selectivity in olefin epoxidation MR Biscoe, R Breslow Journal of the American Chemical Society 127 (31), 10812-10813, 2005 | 55 | 2005 |
Hydrophobically directed selective reduction of ketones MR Biscoe, R Breslow Journal of the American Chemical Society 125 (42), 12718-12719, 2003 | 49 | 2003 |
Stereospecific Palladium‐Catalyzed Acylation of Enantioenriched Alkylcarbastannatranes: A General Alternative to Asymmetric Enolate Reactions CY Wang, G Ralph, J Derosa, MR Biscoe Angewandte Chemie International Edition 56 (3), 856-860, 2017 | 41 | 2017 |
Stereospecific electrophilic fluorination of alkylcarbastannatrane reagents X Ma, M Diane, G Ralph, C Chen, MR Biscoe Angewandte Chemie 129 (41), 12837-12841, 2017 | 28 | 2017 |