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Mark Biscoe
Mark Biscoe
Professor of Chemistry, The City College of New York
Dirección de correo verificada de ccny.cuny.edu - Página principal
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A highly active catalyst for Pd-catalyzed amination reactions: cross-coupling reactions using aryl mesylates and the highly selective monoarylation of primary amines using aryl …
BP Fors, DA Watson, MR Biscoe, SL Buchwald
Journal of the American Chemical Society 130 (41), 13552-13554, 2008
6342008
A new class of easily activated palladium precatalysts for facile C− N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides
MR Biscoe, BP Fors, SL Buchwald
Journal of the American Chemical Society 130 (21), 6686-6687, 2008
5302008
Pd-catalyzed amidations of aryl chlorides using monodentate biaryl phosphine ligands: A kinetic, computational, and synthetic investigation
T Ikawa, TE Barder, MR Biscoe, SL Buchwald
Journal of the American Chemical Society 129 (43), 13001-13007, 2007
3412007
Stereospecific Pd-catalyzed cross-coupling reactions of secondary alkylboron nucleophiles and aryl chlorides
L Li, S Zhao, A Joshi-Pangu, M Diane, MR Biscoe
Journal of the American Chemical Society 136 (40), 14027-14030, 2014
2512014
Structural insights into active catalyst structures and oxidative addition to (biaryl) phosphine− palladium complexes via density functional theory and experimental studies
TE Barder, MR Biscoe, SL Buchwald
Organometallics 26 (9), 2183-2192, 2007
2362007
Nickel-catalyzed Kumada cross-coupling reactions of tertiary alkylmagnesium halides and aryl bromides/triflates
A Joshi-Pangu, CY Wang, MR Biscoe
Journal of the American Chemical Society 133 (22), 8478-8481, 2011
1962011
Enantiodivergent Pd-catalyzed C–C bond formation enabled through ligand parameterization
S Zhao, T Gensch, B Murray, ZL Niemeyer, MS Sigman, MR Biscoe
Science 362 (6415), 670-674, 2018
1932018
Stereoretentive Pd-catalysed Stille cross-coupling reactions of secondary alkyl azastannatranes and aryl halides
L Li, CY Wang, R Huang, MR Biscoe
Nature chemistry 5 (7), 607-612, 2013
1682013
Nickel-catalyzed Negishi cross-coupling reactions of secondary alkylzinc halides and aryl iodides
A Joshi-Pangu, M Ganesh, MR Biscoe
Organic letters 13 (5), 1218-1221, 2011
1272011
Cross Coupling and Heck-Type Reactions 1
GA Molander, MR Biscoe, B Carboni, F Carreaux, WTT Chang, ...
Thieme Verlag, 2013
1242013
Electronic Effects on the Selectivity of Pd‐Catalyzed C N Bond‐Forming Reactions Using Biarylphosphine Ligands: The Competitive Roles of Amine Binding and Acidity
MR Biscoe, TE Barder, SL Buchwald
Angewandte Chemie International Edition 46 (38), 7232-7235, 2007
1242007
Selective monoarylation of acetate esters and aryl methyl ketones using aryl chlorides
MR Biscoe, SL Buchwald
Organic letters 11 (8), 1773-1775, 2009
1152009
Configurationally stable, enantioenriched organometallic nucleophiles in stereospecific Pd-catalyzed cross-coupling reactions: an alternative approach to asymmetric synthesis
CY Wang, J Derosa, MR Biscoe
Chemical science 6 (9), 5105-5113, 2015
992015
Palladium-catalyzed borylation of primary alkyl bromides
A Joshi-Pangu, X Ma, M Diane, S Iqbal, RJ Kribs, R Huang, CY Wang, ...
The Journal of organic chemistry 77 (15), 6629-6633, 2012
842012
Stereoselectivity in Pd-catalysed cross-coupling reactions of enantioenriched nucleophiles
X Ma, B Murray, MR Biscoe
Nature Reviews Chemistry 4 (11), 584-599, 2020
552020
Simple, efficient protocols for the Pd-catalyzed cross-coupling reaction of aryl chlorides and dimethylamine
BK Lee, MR Biscoe, SL Buchwald
Tetrahedron letters 50 (26), 3672-3674, 2009
552009
Oxaziridinium salts as hydrophobic epoxidation reagents: remarkable hydrophobically-directed selectivity in olefin epoxidation
MR Biscoe, R Breslow
Journal of the American Chemical Society 127 (31), 10812-10813, 2005
552005
Hydrophobically directed selective reduction of ketones
MR Biscoe, R Breslow
Journal of the American Chemical Society 125 (42), 12718-12719, 2003
492003
Stereospecific Palladium‐Catalyzed Acylation of Enantioenriched Alkylcarbastannatranes: A General Alternative to Asymmetric Enolate Reactions
CY Wang, G Ralph, J Derosa, MR Biscoe
Angewandte Chemie International Edition 56 (3), 856-860, 2017
412017
Stereospecific electrophilic fluorination of alkylcarbastannatrane reagents
X Ma, M Diane, G Ralph, C Chen, MR Biscoe
Angewandte Chemie 129 (41), 12837-12841, 2017
282017
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Artículos 1–20