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Anthony J. Metrano
Anthony J. Metrano
AstraZeneca Oncology R&D
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Peptide-Based Catalysts Reach the Outer Sphere through Remote Desymmetrization and Atroposelectivity
AJ Metrano, SJ Miller
Accounts of Chemical Research, 2018
2222018
Enantioselective Synthesis of 3-Arylquinazolin-4(3H)-ones via Peptide-Catalyzed Atroposelective Bromination
ME Diener, AJ Metrano, S Kusano, SJ Miller
Journal of the American Chemical Society 137 (38), 12369-12377, 2015
2012015
Spontaneous transfer of chirality in an atropisomerically enriched two-axis system
KT Barrett, AJ Metrano, PR Rablen, SJ Miller
Nature 509 (7498), 71-75, 2014
1632014
Asymmetric Catalysis Mediated by Synthetic Peptides, Version 2.0: Expansion of Scope and Mechanisms
AJ Metrano, AJ Chinn, CR Shugrue, EA Stone, B Kim, SJ Miller
Chemical Reviews, 2020
1522020
Diversity of secondary structure in catalytic peptides with β-turn-biased sequences
AJ Metrano, NC Abascal, BQ Mercado, EK Paulson, AE Hurtley, SJ Miller
Journal of the American Chemical Society 139 (1), 492-516, 2017
1212017
Peptide-Catalyzed Conversion of Racemic Oxazol-5(4H)-ones into Enantiomerically Enriched α-Amino Acid Derivatives
AJ Metrano, SJ Miller
The Journal of Organic Chemistry 79 (4), 1542-1554, 2014
712014
Catalytic Hydroetherification of Unactivated Alkenes Enabled by Proton‐Coupled Electron Transfer
E Tsui, AJ Metrano, Y Tsuchiya, RR Knowles
Angewandte Chemie International Edition 59 (29), 11845-11849, 2020
702020
Parameterization and Analysis of Peptide-Based Catalysts for the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones
JM Crawford, EA Stone, AJ Metrano, SJ Miller, MS Sigman
Journal of the American Chemical Society 140 (3), 868-871, 2018
692018
Desymmetrization of Diarylmethylamido Bis(phenols) through Peptide-Catalyzed Bromination: Enantiodivergence as a Consequence of a 2 amu Alteration at an Achiral Residue within …
AE Hurtley, EA Stone, AJ Metrano, SJ Miller
Journal of Organic Chemistry, 2017
402017
Molecular Dynamics Simulations of a Conformationally Mobile Peptide-Based Catalyst for Atroposelective Bromination
XC Yan, AJ Metrano, MJ Robertson, NC Abascal, J Tirado-Rives, ...
ACS catalysis 8 (11), 9968-9979, 2018
342018
Structural studies of β-turn-containing peptide catalysts for atroposelective quinazolinone bromination
AJ Metrano, NC Abascal, BQ Mercado, EK Paulson, SJ Miller
Chemical Communications 52 (26), 4816-4819, 2016
332016
Detection of weak hydrogen bonding to fluoro and nitro groups in solution using H/D exchange
CR Shugrue, JR DeFrancisco, AJ Metrano, BD Brink, RS Nomoto, ...
Organic & Biomolecular Chemistry 14 (7), 2223-2227, 2016
212016
Troponoid Atropisomerism: Studies on the Configurational Stability of Tropone-Amide Chiral Axes
DR Hirsch, AJ Metrano, EA Stone, G Storch, SJ Miller, RP Murelli
Organic Letters 21, 2019
192019
Isolating conformers to assess dynamics of peptidic catalysts using computationally designed macrocyclic peptides
EA Stone, P Hosseinzadeh, TW Craven, MJ Robertson, Y Han, SY Hsieh, ...
ACS catalysis 11 (8), 4395-4400, 2021
162021
NMR and X-Ray Crystallography-Based Structural Investigations of Peptide Catalysts
NC Abascal, AJ Metrano, PA Lichtor, MW Giuliano, SJ Miller
PROTEIN SCIENCE 25, 150-150, 2016
12016
Catalytic Hydroetherification of Alkenes Mediated by Proton-Coupled Electron Transfer
B List, R Maji
Synfacts 16 (07), 0838, 2020
2020
Development & Study of beta-Turn-Containing Peptides for Enantioselective, Bifunctional Bronsted Base Catalysis
AJ Metrano
Yale University, 2017
2017
Organocatalytic Synthesis of Atropisomers
B List, PSJ Kaib
Synfacts 10 (07), 0761-0761, 2014
2014
Synthesis of enantioenriched alpha-amino acids via peptide-catalyzed dynamic kinetic resoltuion of oxazol-5 (4H)-ones
AJ Metrano, SJ Miller
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 247, 2014
2014
Context-dependent determination of hydrogen bond strength
BR Linton, AJ Metrano, JR DeFrancisco, BD Brink, CR Shugrue, ...
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 243, 2012
2012
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