| Bimetallic Catalysis using Transition and Group 11 Metals: An Emerging Tool for C C Coupling and Other Reactions MH Pérez‐Temprano, JA Casares, P Espinet Chemistry–A European Journal 18 (7), 1864-1884, 2012 | 245 | 2012 |
| C− C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment M Perez-Rodriguez, AAC Braga, M Garcia-Melchor, MH Perez-Temprano, ... Journal of the American Chemical Society 131 (10), 3650-3657, 2009 | 222 | 2009 |
| The mechanism of the Ru-assisted C− C bond cleavage of terminal alkynes by water C Bianchini, JA Casares, M Peruzzini, A Romerosa, F Zanobini Journal of the American Chemical Society 118 (19), 4585-4594, 1996 | 196 | 1996 |
| Insights into the Mechanism of the Negishi Reaction: ZnRX versus ZnR2 Reagents JA Casares, P Espinet, B Fuentes, G Salas Journal of the American Chemical Society 129 (12), 3508-3509, 2007 | 131 | 2007 |
| Palladium Round Trip in the Negishi Coupling of trans‐[PdMeCl(PMePh2)2] with ZnMeCl: An Experimental and DFT Study of the Transmetalation Step B Fuentes, M García‐Melchor, A Lledós, F Maseras, JA Casares, ... Chemistry–A European Journal 16 (29), 8596-8599, 2010 | 84 | 2010 |
| Cationic intermediates in the Pd-catalyzed Negishi coupling. Kinetic and density functional theory study of alternative transmetalation pathways in the Me–Me coupling of ZnMe2 … M Garcia-Melchor, B Fuentes, A Lledos, JA Casares, G Ujaque, P Espinet Journal of the American Chemical Society 133 (34), 13519-13526, 2011 | 83 | 2011 |
| Observation of a slow dissociative process in palladium (II) complexes JA Casares, S Coco, P Espinet, YS Lin Organometallics 14 (6), 3058-3067, 1995 | 78 | 1995 |
| 14‐Electron T‐Shaped [PdRXL] Complexes: Evidence or Illusion? Mechanistic Consequences for the Stille Reaction and Related Processes JA Casares, P Espinet, G Salas Chemistry–A European Journal 8 (21), 4843-4853, 2002 | 73 | 2002 |
| Stille coupling involving bulky groups feasible with gold cocatalyst. J delPozo, D Carrasco, MH Pérez‐Temprano, M García‐Melchor, ... Angewandte Chemie 125 (8), 2013 | 72 | 2013 |
| An Aryl Exchange Reaction with Full Retention of Configuration of the Complexes: Mechanism of the Aryl Exchange between [PdR2L2] Complexes in Chloroform … AL Casado, JA Casares, P Espinet Organometallics 16 (26), 5730-5736, 1997 | 72 | 1997 |
| 19F NMR in organometallic chemistry: Applications of fluorinated aryls P Espinet, AC Albéniz, JA Casares, JM Martínez-Ilarduya Coordination Chemistry Reviews 252 (21-22), 2180-2208, 2008 | 71 | 2008 |
| Strong metallophilic interactions in the palladium arylation by gold aryls. MH Pérez-Temprano, JA Casares, ÁR de Lera, R Álvarez, P Espinet Angewandte Chemie (International ed. in English) 51 (20), 4917-4920, 2012 | 60 | 2012 |
| Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and Time-Resolved Studies R Osman, DI Pattison, RN Perutz, C Bianchini, JA Casares, M Peruzzini Journal of the American Chemical Society 119 (36), 8459-8473, 1997 | 56 | 1997 |
| Efficient rhodium catalysts for the hydrogenolysis of thiophenic molecules in homogeneous phase C Bianchini, JA Casares, A Meli, V Sernau, F Vizza, RA Sánchez-Delgado Polyhedron 16 (18), 3099-3114, 1997 | 55 | 1997 |
| Kinetic Study of the Dynamic Behavior of [M(C6F5)X(OPPynPh3-n)] (M = Pd, Pt; X = C6F5, Halide; n = 1−3): Activation Parameters for the Restricted … JA Casares, P Espinet, JM Martínez-Ilarduya, YS Lin Organometallics 16 (4), 770-779, 1997 | 54 | 1997 |
| The Negishi catalysis: full study of the complications in the transmetalation step and consequences for the coupling products J del Pozo, G Salas, R Álvarez, JA Casares, P Espinet Organometallics 35 (20), 3604-3611, 2016 | 53 | 2016 |
| Poly(2-pyridyl)phosphines, PPynPh3-n (n = 2, 3), and Their P-Substituted Derivatives as Tripodal Ligands in Molybdenum(0) Carbonyl Complexes JA Casares, P Espinet, R Hernando, G Iturbe, F Villafañe, DD Ellis, ... Inorganic Chemistry 36 (1), 44-49, 1997 | 51 | 1997 |
| Dynamic Behavior of [Pd(C6F5)2(SPPynPh3-n)] Complexes: Evidence for a Turnstile Mechanism in Intramolecular Exchange JA Casares, P Espinet Inorganic Chemistry 36 (24), 5428-5431, 1997 | 49 | 1997 |
| P(CH2CH2Py)nPh3-n (Py = 2-Pyridyl; n = 1, 2, 3) as Chelating and as Binucleating Ligands for Palladium JA Casares, P Espinet, K Soulantica, I Pascual, AG Orpen Inorganic Chemistry 36 (23), 5251-5256, 1997 | 49 | 1997 |
| Observation of a hidden intermediate in the Stille reaction. Study of the reversal of the transmetalation step MH Pérez-Temprano, A Nova, JA Casares, P Espinet Journal of the American Chemical Society 130 (32), 10518-10520, 2008 | 46 | 2008 |
