A Synthetic Model of Enzymatic [Fe4S4]–Alkyl Intermediates M Ye, NB Thompson, AC Brown, DLM Suess Journal of the American Chemical Society 141 (34), 13330-13335, 2019 | 57 | 2019 |
Evidence for Low-Valent Electronic Configurations in Iron–Sulfur Clusters AC Brown, NB Thompson, DLM Suess Journal of the American Chemical Society 144 (20), 9066-9073, 2022 | 45 | 2022 |
Chemical structure and bonding in a thorium (iii)–aluminum heterobimetallic complex AB Altman, AC Brown, G Rao, TD Lohrey, RD Britt, L Maron, SG Minasian, ... Chemical Science 9 (18), 4317-4324, 2018 | 42 | 2018 |
A terminal imido complex of an iron–sulfur cluster A Sridharan, AC Brown, DLM Suess Angewandte Chemie 133 (23), 12912-12916, 2021 | 33 | 2021 |
Reversible Formation of Alkyl Radicals at [Fe4S4] Clusters and Its Implications for Selectivity in Radical SAM Enzymes AC Brown, DLM Suess Journal of the American Chemical Society, 2020 | 32 | 2020 |
Controlling Substrate Binding to Fe4S4 Clusters through Remote Steric Effects AC Brown, DLM Suess Inorganic chemistry 58 (8), 5273-5280, 2019 | 31 | 2019 |
Hydride oxidation from a titanium–aluminum bimetallic complex: insertion, thermal and electrochemical reactivity AC Brown, AB Altman, TD Lohrey, S Hohloch, J Arnold Chemical science 8 (7), 5153-5160, 2017 | 30 | 2017 |
Metal Bonding with 3d and 6d Orbitals: An EPR and ENDOR Spectroscopic Investigation of Ti3+–Al and Th3+–Al Heterobimetallic Complexes G Rao, AB Altman, AC Brown, L Tao, TA Stich, J Arnold, RD Britt Inorganic chemistry 58 (12), 7978-7988, 2019 | 21 | 2019 |
Valence Localization in Alkyne and Alkene Adducts of Synthetic [Fe4S4]+ Clusters AC Brown, DLM Suess Inorganic chemistry 62 (5), 1911-1918, 2022 | 14 | 2022 |
Reversible Alkyl-Group Migration between Iron and Sulfur in [Fe4S4] Clusters M Ye, AC Brown, DLM Suess Journal of the American Chemical Society 144 (29), 13184-13195, 2022 | 12 | 2022 |
An Iron–Sulfur Cluster with a Highly Pyramidalized Three-Coordinate Iron Center and a Negligible Affinity for Dinitrogen AC Brown, DLM Suess Journal of the American Chemical Society 145 (36), 20088-20096, 2023 | 11 | 2023 |
An Open-Cuboidal [Fe3S4] Cluster Characterized in Both Biologically Relevant Redox States AC Brown, DLM Suess Journal of the American Chemical Society 145 (4), 2075-2080, 2023 | 9 | 2023 |
Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit S Kampouri, M Zhang, T Chen, JJ Oppenheim, AC Brown, MT Payne, ... Angewandte Chemie International Edition 61 (49), e202213960, 2022 | 8 | 2022 |
Synthetic Iron-Sulfur Clusters AC Brown, DLM Suess Elsevier, 2021 | 8 | 2021 |
A general method for metallocluster site-differentiation TM Bostelaar, AC Brown, A Sridharan, DLM Suess Nature Synthesis 2 (8), 740-748, 2023 | 6 | 2023 |
Activation of Strong π–Acids at [Fe4S4]+ Clusters Enabled by a Noncanonical Electronic Structure AC Brown, NB Thompson, DLM Suess Journal of the American Chemical Society 146 (49), 34080-34091, 2024 | | 2024 |
Coordination Chemistry of Fe–S Clusters Supported by N-Heterocyclic Carbenes AC Brown Massachusetts Institute of Technology, 2023 | | 2023 |