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Alexandra C. Brown
Alexandra C. Brown
Preverjeni e-poštni naslov na mit.edu
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Leto
A Synthetic Model of Enzymatic [Fe4S4]–Alkyl Intermediates
M Ye, NB Thompson, AC Brown, DLM Suess
Journal of the American Chemical Society 141 (34), 13330-13335, 2019
572019
Evidence for Low-Valent Electronic Configurations in Iron–Sulfur Clusters
AC Brown, NB Thompson, DLM Suess
Journal of the American Chemical Society 144 (20), 9066-9073, 2022
452022
Chemical structure and bonding in a thorium (iii)–aluminum heterobimetallic complex
AB Altman, AC Brown, G Rao, TD Lohrey, RD Britt, L Maron, SG Minasian, ...
Chemical Science 9 (18), 4317-4324, 2018
422018
A terminal imido complex of an iron–sulfur cluster
A Sridharan, AC Brown, DLM Suess
Angewandte Chemie 133 (23), 12912-12916, 2021
332021
Reversible Formation of Alkyl Radicals at [Fe4S4] Clusters and Its Implications for Selectivity in Radical SAM Enzymes
AC Brown, DLM Suess
Journal of the American Chemical Society, 2020
322020
Controlling Substrate Binding to Fe4S4 Clusters through Remote Steric Effects
AC Brown, DLM Suess
Inorganic chemistry 58 (8), 5273-5280, 2019
312019
Hydride oxidation from a titanium–aluminum bimetallic complex: insertion, thermal and electrochemical reactivity
AC Brown, AB Altman, TD Lohrey, S Hohloch, J Arnold
Chemical science 8 (7), 5153-5160, 2017
302017
Metal Bonding with 3d and 6d Orbitals: An EPR and ENDOR Spectroscopic Investigation of Ti3+–Al and Th3+–Al Heterobimetallic Complexes
G Rao, AB Altman, AC Brown, L Tao, TA Stich, J Arnold, RD Britt
Inorganic chemistry 58 (12), 7978-7988, 2019
212019
Valence Localization in Alkyne and Alkene Adducts of Synthetic [Fe4S4]+ Clusters
AC Brown, DLM Suess
Inorganic chemistry 62 (5), 1911-1918, 2022
142022
Reversible Alkyl-Group Migration between Iron and Sulfur in [Fe4S4] Clusters
M Ye, AC Brown, DLM Suess
Journal of the American Chemical Society 144 (29), 13184-13195, 2022
122022
An Iron–Sulfur Cluster with a Highly Pyramidalized Three-Coordinate Iron Center and a Negligible Affinity for Dinitrogen
AC Brown, DLM Suess
Journal of the American Chemical Society 145 (36), 20088-20096, 2023
112023
An Open-Cuboidal [Fe3S4] Cluster Characterized in Both Biologically Relevant Redox States
AC Brown, DLM Suess
Journal of the American Chemical Society 145 (4), 2075-2080, 2023
92023
Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit
S Kampouri, M Zhang, T Chen, JJ Oppenheim, AC Brown, MT Payne, ...
Angewandte Chemie International Edition 61 (49), e202213960, 2022
82022
Synthetic Iron-Sulfur Clusters
AC Brown, DLM Suess
Elsevier, 2021
82021
A general method for metallocluster site-differentiation
TM Bostelaar, AC Brown, A Sridharan, DLM Suess
Nature Synthesis 2 (8), 740-748, 2023
62023
Activation of Strong π–Acids at [Fe4S4]+ Clusters Enabled by a Noncanonical Electronic Structure
AC Brown, NB Thompson, DLM Suess
Journal of the American Chemical Society 146 (49), 34080-34091, 2024
2024
Coordination Chemistry of Fe–S Clusters Supported by N-Heterocyclic Carbenes
AC Brown
Massachusetts Institute of Technology, 2023
2023
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