Heteroatom-based diradical (oid) s
Heteroatom-centered diradical (oid) s have been in the focus of molecular main group
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …
Bis-[cyclic (alkyl)(amino) carbene]-derived diradicals
Crystalline polymeric structures of trans-1, 4-cyclohexylene bridged N-tethered bis-CAACs
in the form of their LiOTf adducts were synthesized and isolated. These were further used as …
in the form of their LiOTf adducts were synthesized and isolated. These were further used as …
A class of non-aromatic 1, 3-disilapyrroles acting as stable organosilicon-based triplet diradicals
Open-shell molecules with unpaired electrons and a high-spin S≥ 1 configuration are of
fundamental importance in chemistry, biology and molecular electronics. Among metal-free …
fundamental importance in chemistry, biology and molecular electronics. Among metal-free …
Introducing an orthogonally polarized electron-rich alkene: synthesis of a zwitterionic boron-containing π-conjugated system
N Chrysochos, S Pätsch, BJ Elvers… - Chemical …, 2023 - pubs.rsc.org
The synthesis of an alkene is reported which is concurrently twisted (twist angle= 86.6 (8)°),
push–pull (dipole moment= 7.48 D), and electron-rich (E1/2=− 1.45 V and− 0.52 V vs …
push–pull (dipole moment= 7.48 D), and electron-rich (E1/2=− 1.45 V and− 0.52 V vs …
Reduction of 2-H-substituted pyrrolinium cations: the carbon–carbon single bond in air stable 2, 2′-bipyrrolidines as a two-electron-source
Reduction of 2-H-substituted pyrrolinium cations via initially formed secondary radicals
results in either dimerisation or H-abstracted products, while the outcome depends on the N …
results in either dimerisation or H-abstracted products, while the outcome depends on the N …
Bis‐Olefin Based Crystalline Schlenk Hydrocarbon Diradicals with a Triplet Ground State
P Saha, N Chrysochos, BJ Elvers… - Angewandte Chemie …, 2023 - Wiley Online Library
A modular approach for the synthesis of isolable crystalline Schlenk hydrocarbon diradicals
from m‐phenylene bridged electron‐rich bis‐triazaalkenes as synthons is reported. EPR …
from m‐phenylene bridged electron‐rich bis‐triazaalkenes as synthons is reported. EPR …
N‐Heterocyclic Carbene Analogues of Wittig Hydrocarbon
H Steffenfauseweh, YV Vishnevskiy… - … A European Journal, 2024 - Wiley Online Library
N‐Heterocyclic carbene (NHC) analogues of Wittig hydrocarbon,[(NHC)(Stil)(NHC)](3a‐
c)(NHC= SIPr (1a)= C [N (Dipp) CH2] 2, Dipp= 2, 6‐iPr2C6H3; IPr (1b)= C [N (Dipp) CH] 2; …
c)(NHC= SIPr (1a)= C [N (Dipp) CH2] 2, Dipp= 2, 6‐iPr2C6H3; IPr (1b)= C [N (Dipp) CH] 2; …
Von bis‐Olefin‐abgeleitete kristalline, diradikalische Schlenk‐Kohlenwasserstoffe mit einem Triplett‐Grundzustand
P Saha, N Chrysochos, BJ Elvers, S Pätsch… - Angewandte …, 2023 - Wiley Online Library
Beschrieben wird ein modularer Ansatz für die Synthese von kristallinen, diradikalischen
Schlenk‐Kohlenwasserstoffen ausgehend von m‐Phenylen‐verbrückten, elektronenreichen …
Schlenk‐Kohlenwasserstoffen ausgehend von m‐Phenylen‐verbrückten, elektronenreichen …
Azide‐substituted 1, 2, 3‐triazolium salts as useful synthetic synthons: access to triazenyl radicals and Staudinger type reactivity
Mesoionic carbenes (MIC) are a popular class of compound that are heavily investigated at
the moment. The access to cationic MICs, and the ability of MICs to stabilize radicals are two …
the moment. The access to cationic MICs, and the ability of MICs to stabilize radicals are two …
[CITAS][C] Pentamethylcyclopentadienyl-Halbsandwich-Eisenkomplexe mit ungewöhnlichen Carbenliganden
J Zinke - 2024