Data-efficient fine-tuning of foundational models for first-principles quality sublimation enthalpies

H Kaur, F Della Pia, I Batatia, XR Advincula… - Faraday …, 2025 - pubs.rsc.org
Calculating sublimation enthalpies of molecular crystal polymorphs is relevant to a wide
range of technological applications. However, predicting these quantities at first-principles …

Multi-GPU RI-HF Energies and Analytic Gradients─ Toward High-Throughput Ab Initio Molecular Dynamics

R Stocks, E Palethorpe, GMJ Barca - Journal of Chemical Theory …, 2024 - ACS Publications
This article presents an optimized algorithm and implementation for calculating resolution-of-
the-identity Hartree–Fock (RI-HF) energies and analytic gradients using multiple graphics …

[HTML][HTML] Massively parallel implementation of gradients within the random phase approximation: Application to the polymorphs of benzene

F Stein, J Hutter - The Journal of Chemical Physics, 2024 - pubs.aip.org
The Random-Phase approximation (RPA) provides an appealing framework for semi-local
density functional theory. In its Resolution-of-the-Identity (RI) approach, it is a very accurate …

[HTML][HTML] Efficient periodic resolution-of-the-identity Hartree–Fock exchange method with k-point sampling and Gaussian basis sets

A Bussy, J Hutter - The Journal of Chemical Physics, 2024 - pubs.aip.org
Simulations of condensed matter systems at the hybrid density functional theory level pose
significant computational challenges. The elevated costs arise from the non-local nature of …

Predicting the charge density response in metal electrodes

A Grisafi, A Bussy, M Salanne, R Vuilleumier - Physical Review Materials, 2023 - APS
The computational study of energy storage and conversion processes calls for simulation
techniques that can reproduce the electronic response of metal electrodes under electric …

To pair or not to pair? Machine-learned explicitly-correlated electronic structure for NaCl in water

N O'Neill, BX Shi, K Fong, A Michaelides… - The Journal of …, 2024 - ACS Publications
The extent of ion pairing in solution is an important phenomenon to rationalize transport and
thermodynamic properties of electrolytes. A fundamental measure of this pairing is the …

Static Subspace Approximation for Random Phase Approximation Correlation Energies: Implementation and Performance

D Weinberg, OA Hull, JM Clary… - Journal of Chemical …, 2024 - ACS Publications
Develo** theoretical understanding of complex reactions and processes at interfaces
requires using methods that go beyond semilocal density functional theory to accurately …

Validation of the GreenX library time-frequency component for efficient and RPA calculations

M Azizi, J Wilhelm, D Golze, FA Delesma… - Physical Review B, 2024 - APS
Electronic structure calculations based on many-body perturbation theory [eg, GW or the
random-phase approximation (RPA)] require function evaluations in the complex time and …

Enabling 13K-Atom Excited-State GW Calculations via Low-Rank Approximations and HPC on the New Sunway Supercomputer

W Wu, Z Zhou, Q Jiang, J Feng, X Qin… - … Conference for High …, 2024 - ieeexplore.ieee.org
GW approximation is a powerful approach to accurately describe the excited-state of
semiconductors. However, GW incurs high computational cost O\left(N^4\right) and large …

Accelerating QM/MM simulations of electrochemical interfaces through machine learning of electronic charge densities

A Grisafi, M Salanne - arxiv preprint arxiv:2405.07370, 2024 - arxiv.org
A crucial aspect in the simulation of electrochemical interfaces consists in treating the
distribution of electronic charge of electrode materials that are put in contact with an …