Fluoropolymers have unique physicochemical properties such as hydrophobicity and
lipophobicity, good chemical stability and bio-inertness, low surface energy and phase …

Unlike natural macromolecules (eg, nucleic acids and proteins) possessing precisely
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …

This review describes different synthetic strategies towards sequence‐defined,
monodisperse macromolecules, which are built up by iterative approaches and lead to …

Highlights•New assembly approaches of DNA nanostructures with increased complexity.•
Biotechnological approaches for improved scalability of DNA assembly.•Blunt-end stacking …

The development of nucleic acid therapeutics has been hampered by issues associated with
their stability and in vivo delivery. To address these challenges, we describe a new strategy …

Hypoxia is a key impediment encountered in the treatment of most solid tumors, leading to
immune escape and therapeutic resistance. Perfluorocarbons (PFCs) have a unique …

Conventional grafting-to approaches to DNA–polymer conjugates are often limited by low
reaction yields due to the sterically hindered coupling of a presynthesized polymer to DNA …

Sequence‐coded polyurethanes are tested as anticounterfeiting tags for the labeling of
methacrylate‐based intraocular implants. These sequence‐defined oligomers are prepared …

A three‐step post‐polymerization modification method was developed for the design of
digitally encoded poly (phosphodiester) s with controllable side groups. Sequence‐defined …

Conspectus Millions of years of biological evolution have driven the development of highly
sophisticated molecular machinery found within living systems. These systems produce …