Triplet pair states in singlet fission

K Miyata, FS Conrad-Burton, FL Geyer… - Chemical reviews, 2019 - ACS Publications
This account aims at providing an understanding of singlet fission, ie, the photophysical
process of a singlet state (S1) splitting into two triplet states (2× T1) in molecular …

Theoretical modeling of singlet fission

D Casanova - Chemical reviews, 2018 - ACS Publications
Singlet fission is a photophysical reaction in which a singlet excited electronic state splits
into two spin-triplet states. Singlet fission was discovered more than 50 years ago, but the …

Spin-flip methods in quantum chemistry

D Casanova, AI Krylov - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
This Perspective discusses salient features of the spin-flip approach to strong correlation
and describes different methods that sprung from this idea. The spin-flip treatment exploits …

Leveraging charge-transfer interactions in through-space-coupled pentacene dendritic oligomer for singlet exciton fission

J Kim, HT Teo, Y Hong, YC Liau, D Yim… - Journal of the …, 2023 - ACS Publications
Singlet exciton fission in organic chromophores has received much attention during the past
decade. Inspired by numerous spectroscopic studies in the solid state, there have been …

Efficient multiexciton state generation in charge-transfer-coupled perylene bisimide dimers via structural control

Y Hong, J Kim, W Kim, C Kaufmann, H Kim… - Journal of the …, 2020 - ACS Publications
The singlet fission (SF) process is generally defined as the conversion of one singlet exciton
(S1) into two triplet excitons (2· T1), which has the potential to overcome thermalization …

Linker-dependent singlet fission in tetracene dimers

NV Korovina, J Joy, X Feng… - Journal of the …, 2018 - ACS Publications
Separation of triplet excitons produced by singlet fission is crucial for efficient application of
singlet fission materials. While earlier works explored the first step of singlet fission, the …

Lessons from intramolecular singlet fission with covalently bound chromophores

NV Korovina, NF Pompetti, JC Johnson - The Journal of chemical …, 2020 - pubs.aip.org
Molecular dimers, oligomers, and polymers are versatile components in photophysical and
optoelectronic architectures that could impact a variety of applications. We present a …

Striking the right balance of intermolecular coupling for high-efficiency singlet fission

RD Pensack, AJ Tilley, C Grieco, GE Purdum… - Chemical …, 2018 - pubs.rsc.org
Singlet fission is a process that splits collective excitations, or excitons, into two with unity
efficiency. This exciton splitting process, unique to molecular photophysics, has the potential …

Coupled double triplet state in singlet fission

H Kim, PM Zimmerman - Physical Chemistry Chemical Physics, 2018 - pubs.rsc.org
The highly unusual state, 1 (TT), is a coupled, double triplet state that has recently garnered
significant attention. This multiexcitonic state can be formed by a quantum transition from a …

Distinct properties of the triplet pair state from singlet fission

MT Trinh, A Pinkard, AB Pun, SN Sanders… - Science …, 2017 - science.org
Singlet fission, the conversion of a singlet exciton (S1) to two triplets (2× T1), may increase
the solar energy conversion efficiency beyond the Shockley-Queisser limit. This process is …