Natural product synthesis has lain at the heart of organic chemistry. Complex structures of
natural products have inspired chemists to develop new methods and strategies. The utility …

Total synthesis of natural products has been an important pursuit in chemical synthesis due
to their fascinating structural complexity and/or interesting biological activities. In most …

Interest in therapeutic discovery typically drives the preparation of natural product analogs,
but these undertakings contribute significant advances for synthetic chemistry as well. The …

A new strategy focusing on the last-stage asymmetric assembly of the ring D, which
inherently possesses the densest part of stereogenic centers and functional groups in the …

A catalytic enantioselective polycyclization of tertiary enamides with terminal silyl enol ethers
has been developed by virtue of Cu (OTf) 2 catalysis with a novel spiropyrroline-derived …

Based on rich sulfur-involving chemical transformations, a novel spokewise synthetic
strategy, a subclass of the collective strategies, has been developed to concisely synthesize …

Bioinspired palladium‐catalyzed intramolecular cyclization of amino acid derivatives
containing a vinyl iodide moiety by C− H activation enabled rapid access to a wide range of …

Covering: 2013 to 2023 The α-tertiary amine moiety is a common structural motif in natural
alkaloids and is frequently associated with intriguing biological activities and inherent …

A Cu-catalyzed diastereoselective [3+ 2] cycloaddition of 2-arylaziridines and cyclic silyl
dienol ethers was developed to efficiently construct fused-[5, n] carbocyclic pyrrolidines …

Over the past decades, scientists have obtained a diverse range of interesting natural
products, including alkaloids, terpenoids, and flavonoids from the genus Cephalotaxus …