N-heterocyclic carbene transition metal complexes for catalysis in aqueous media

HD Velazquez, F Verpoort - Chemical Society Reviews, 2012 - pubs.rsc.org
The last decade has seen an increasing number of reports on the use of NHC–metal
complexes for catalysis in water, therefore this review is aimed to introduce the whole …

Water in N-heterocyclic carbene-assisted catalysis

E Levin, E Ivry, CE Diesendruck, NG Lemcoff - Chemical reviews, 2015 - ACS Publications
Water is one of the most abundant molecules on earth. It is inexpensive, especially when
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …

Palladium catalysts with Sulfonate-functionalized-NHC ligands for Suzuki− Miyaura cross-coupling reactions in water

F Godoy, C Segarra, M Poyatos, E Peris - Organometallics, 2011 - ACS Publications
Four new Pd (II) complexes containing sulfonate-functionalized N-heterocyclic carbene
ligands have been synthesized. All new complexes are palladium bis-NHCs, in which the …

Organosulphur and related ligands in Suzuki–Miyaura C–C coupling

A Kumar, GK Rao, S Kumar, AK Singh - Dalton Transactions, 2013 - pubs.rsc.org
Suzuki–Miyaura C–C cross coupling (SMC), an important synthetic strategy for many
organic molecules, has several advantages such as mild reaction conditions, high tolerance …

Sulfur-Functionalized N-Heterocyclic Carbene Complexes of Pd(II): Syntheses, Structures and Catalytic Activities

D Yuan, HV Huynh - Molecules, 2012 - mdpi.com
N-heterocyclic carbenes (NHCs) can be easily modified by introducing functional groups at
the nitrogen atoms, which leads to versatile coordination chemistry as well as diverse …

Magnetic chitosan stabilized palladium nanostructures: Potential catalysts for aqueous Suzuki coupling reactions

N Shaikh, P Pamidimukkala - International Journal of Biological …, 2021 - Elsevier
This work describes the preparation of palladium-based catalyst supported on magnetic
chitosan (Pd@ IO-Chitosan) for Suzuki Miyaura CC coupling reaction. The Pd@ IO-Chitosan …

Mixed phosphine/N-heterocyclic carbene palladium complexes: synthesis, characterization and catalytic use in aqueous Suzuki–Miyaura reactions

TE Schmid, DC Jones, O Songis, O Diebolt… - Dalton …, 2013 - pubs.rsc.org
A series of N-heterocyclic carbene (NHC)/PR3 palladium (II) and palladium (0) complexes
has been synthesized and fully characterized. X-ray crystallographic data have allowed …

Sulfonate-functionalized NHC-based ruthenium catalysts for the isomerization of allylic alcohols in water. Recyclability studies

A Azua, S Sanz, E Peris - Organometallics, 2010 - ACS Publications
Two new complexes of the type [Ru (CO3)(η6-arene)(NHC)] Cs, in which the NHC ligand
incorporates a sulfonate functionality, have been prepared and fully characterized. The two …

The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters

JA Cabeza, P García-Álvarez - Chemical Society Reviews, 2011 - pubs.rsc.org
In the last decade, chemists have dedicated many efforts to investigate the coordination
chemistry of N-heterocyclic carbenes (NHCs). Although most of that research activity has …

Palladium (ii) complexes bearing the 1, 2, 3-triazole based organosulfur/selenium ligand: synthesis, structure and applications in Heck and Suzuki–Miyaura coupling …

F Saleem, GK Rao, A Kumar, S Kumar, MP Singh… - RSC …, 2014 - pubs.rsc.org
Air and moisture insensitive palladium complexes,[Pd (L) Cl2](1/2), in which L= 1-benzyl-4-
phenylthiomethyl or 1-benzyl-4-phenylselenomethyl-1H-1, 2, 3-triazole (L1 or L2) catalyze …