Hydroamination: direct addition of amines to alkenes and alkynes

TE Muller, KC Hultzsch, M Yus, F Foubelo… - Chemical …, 2008 - ACS Publications
Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters

DM Lyubov, AO Tolpygin, AA Trifonov - Coordination Chemistry Reviews, 2019 - Elsevier
Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters -
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Polymerization of lactide and related cyclic esters by discrete metal complexes

BJ O'Keefe, MA Hillmyer, WB Tolman - Journal of the Chemical Society …, 2001 - pubs.rsc.org
This perspective highlights recent research on the preparation of polyesters by the ring-
opening polymerization of cyclic esters employing well-characterized metal complexes …

Chiral lanthanide complexes: coordination chemistry and applications

HC Aspinall - Chemical reviews, 2002 - ACS Publications
The classical examples of chirality in coordination chemistry are transition-metal chelate
complexes of the type [M (bidentate) 3] that exist in nonsuperimposable mirror image forms …

Recent developments in organolanthanide polymerization catalysts

Z Hou, Y Wakatsuki - Coordination Chemistry Reviews, 2002 - Elsevier
This review describes recent advances in the synthesis and polymerization chemistry of
organolanthanide complexes (including those of scandium and yttrium), with emphasis …

Transition metal‐catalyzed asymmetric hydroamination of alkenes (AHA)

KC Hultzsch - Advanced Synthesis & Catalysis, 2005 - Wiley Online Library
The hydroamination of unsaturated carbon‐carbon linkages allows a facile and highly atom‐
economical access to industrially relevant nitrogen‐containing basic and fine chemicals as …

Synthesis and degradation behavior of cyclic poly (ε-caprolactone)

JN Hoskins, SM Grayson - Macromolecules, 2009 - ACS Publications
Narrow polydisersity cyclic poly (caprolactone) was synthesized by cyclization of linear α, ω-
functionalized poly (caprolactone). The linear precursors were prepared via ring-opening …

Ring-opening polymerization by lithium catalysts: an overview

AK Sutar, T Maharana, S Dutta, CT Chen… - Chemical Society …, 2010 - pubs.rsc.org
This critical review summarizes recent developments in the preparation and application of
lithium catalysts/initiators such as, alkyl lithium, alkoxy lithium and bimetallic lithium …

Single-Component Polymerization Catalysts for Ethylene and Styrene: Synthesis, Characterization, and Reactivity of Alkyl and Hydrido Yttrium Complexes Containing …

KC Hultzsch, P Voth, K Beckerle, TP Spaniol… - …, 2000 - ACS Publications
Yttrium alkyl complexes Y (η5: η1-C5Me4SiMe2NCMe2R)(CH2SiMe3)(THF)(R= Me, Et) and
Y (η5: η1-C9H6SiMe2NCMe3)(CH2SiMe3)(THF) can be prepared in high yields by a σ …

Synthesis and Characterization of New Biphenolate and Binaphtholate Rare‐Earth‐Metal Amido Complexes: Catalysts for Asymmetric Olefin Hydroamination …

DV Gribkov, KC Hultzsch… - Chemistry–A European …, 2003 - Wiley Online Library
Monomeric diolate amido yttrium complexes [Y {diolate}{N (SiHMe2) 2}(thf) 2] can be
prepared in good yield by treating [Y {N (SiHMe2) 2} 3 (thf) 2] with either 3, 3′‐di‐tert‐butyl …