Knotting matters: orderly molecular entanglements
Entangling strands in a well-ordered manner can produce useful effects, from shoelaces and
fishing nets to brown paper packages tied up with strings. At the nanoscale, non-crystalline …
fishing nets to brown paper packages tied up with strings. At the nanoscale, non-crystalline …
Molecular weaving
Historically, the interlacing of strands at the molecular level has mainly been limited to
coordination polymers and DNA. Despite being proposed on a number of occasions, the …
coordination polymers and DNA. Despite being proposed on a number of occasions, the …
Guest-driven self-assembly and chiral induction of photofunctional lanthanide tetrahedral cages
SJ Hu, XQ Guo, LP Zhou, DN Yan… - Journal of the …, 2022 - ACS Publications
Chiral luminescent lanthanide–organic cages have many potential applications in
enantioselective recognition, sensing, and asymmetric catalysis. However, due to the …
enantioselective recognition, sensing, and asymmetric catalysis. However, due to the …
Self-Assembly and photothermal conversion of metallarussian doll and metalla [2] catenanes induced via multiple stacking interactions
T Chen, Y Zhao, LL Dang, TT Zhang… - Journal of the …, 2023 - ACS Publications
A variety of organometallic supramolecular architectures have been constructed over the
past decades and their properties were also explored via different strategies. However, the …
past decades and their properties were also explored via different strategies. However, the …
Homochiral porous metal–organic polyhedra with multiple kinds of vertices
Metal–organic polyhedra featuring non-Archimedean/Platonic architectures with multiple
kinds of vertices have aroused great attention for their fascinating structures and properties …
kinds of vertices have aroused great attention for their fascinating structures and properties …
Recent trends in organic cage synthesis: push towards water-soluble organic cages
Research on organic cages has blossomed over the past few years into a mature field of
study which can contribute to solving some of the challenging problems. In this review we …
study which can contribute to solving some of the challenging problems. In this review we …
The codriven assembly of molecular metalla-links (, ) and metalla-knots (, ) via coordination and noncovalent interactions
SJ Bao, Y Zou, HN Zhang, GX ** - … of the National Academy of Sciences, 2024 - pnas.org
Although mechanically interlocked molecules (MIMs) display unique properties and
functions associated with their intricate connectivity, limited assembly strategies are …
functions associated with their intricate connectivity, limited assembly strategies are …
A catenane that is topologically achiral despite being composed of oriented rings
Catenanes—molecules comprising two interlocking rings held together like links in a chain—
are topologically non-trivial: a catenane is a topological isomer of its separated rings, but the …
are topologically non-trivial: a catenane is a topological isomer of its separated rings, but the …
Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …
work in this area has focused on the formation of hollow self-assembled metal-organic …
Vernier template synthesis of molecular knots
Molecular knots are often prepared using metal helicates to cross the strands. We found that
coordinatively mismatching oligodentate ligands and metal ions provides a more effective …
coordinatively mismatching oligodentate ligands and metal ions provides a more effective …