Knotting matters: orderly molecular entanglements

Z Ashbridge, SDP Fielden, DA Leigh, L Pirvu… - Chemical Society …, 2022 - pubs.rsc.org
Entangling strands in a well-ordered manner can produce useful effects, from shoelaces and
fishing nets to brown paper packages tied up with strings. At the nanoscale, non-crystalline …

Molecular weaving

ZH Zhang, BJ Andreassen, DP August, DA Leigh… - Nature Materials, 2022 - nature.com
Historically, the interlacing of strands at the molecular level has mainly been limited to
coordination polymers and DNA. Despite being proposed on a number of occasions, the …

Guest-driven self-assembly and chiral induction of photofunctional lanthanide tetrahedral cages

SJ Hu, XQ Guo, LP Zhou, DN Yan… - Journal of the …, 2022 - ACS Publications
Chiral luminescent lanthanide–organic cages have many potential applications in
enantioselective recognition, sensing, and asymmetric catalysis. However, due to the …

Self-Assembly and photothermal conversion of metallarussian doll and metalla [2] catenanes induced via multiple stacking interactions

T Chen, Y Zhao, LL Dang, TT Zhang… - Journal of the …, 2023 - ACS Publications
A variety of organometallic supramolecular architectures have been constructed over the
past decades and their properties were also explored via different strategies. However, the …

Homochiral porous metal–organic polyhedra with multiple kinds of vertices

X Tang, C Meng, N Rampal, A Li, X Chen… - Journal of the …, 2023 - ACS Publications
Metal–organic polyhedra featuring non-Archimedean/Platonic architectures with multiple
kinds of vertices have aroused great attention for their fascinating structures and properties …

Recent trends in organic cage synthesis: push towards water-soluble organic cages

D Chakraborty, PS Mukherjee - Chemical Communications, 2022 - pubs.rsc.org
Research on organic cages has blossomed over the past few years into a mature field of
study which can contribute to solving some of the challenging problems. In this review we …

The codriven assembly of molecular metalla-links (, ) and metalla-knots (, ) via coordination and noncovalent interactions

SJ Bao, Y Zou, HN Zhang, GX ** - … of the National Academy of Sciences, 2024 - pnas.org
Although mechanically interlocked molecules (MIMs) display unique properties and
functions associated with their intricate connectivity, limited assembly strategies are …

A catenane that is topologically achiral despite being composed of oriented rings

N Pairault, F Rizzi, D Lozano, EMG Jamieson… - Nature Chemistry, 2023 - nature.com
Catenanes—molecules comprising two interlocking rings held together like links in a chain—
are topologically non-trivial: a catenane is a topological isomer of its separated rings, but the …

Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes

CT McTernan, JA Davies, JR Nitschke - Chemical Reviews, 2022 - ACS Publications
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …

Vernier template synthesis of molecular knots

Z Ashbridge, E Kreidt, L Pirvu, F Schaufelberger… - Science, 2022 - science.org
Molecular knots are often prepared using metal helicates to cross the strands. We found that
coordinatively mismatching oligodentate ligands and metal ions provides a more effective …