Designing electrolytes and interphases for high-energy lithium batteries

H Wan, J Xu, C Wang - Nature Reviews Chemistry, 2024 - nature.com
High-energy and stable lithium-ion batteries are desired for next-generation electric devices
and vehicles. To achieve their development, the formation of stable interfaces on high …

Reviewing failure mechanisms and modification strategies in stabilizing high-voltage LiCoO2 cathodes beyond 4.55 V

R Konar, S Maiti, N Shpigel, D Aurbach - Energy Storage Materials, 2023 - Elsevier
Lithium cobalt oxide (LiCoO 2 or LCO) is undoubtedly one of the best commercial cathode
materials for Lithium-ion batteries (LIBs). High energy density, excellent cycle life, and long …

Fluorinated Li10GeP2S12 Enables Stable All‐Solid‐State Lithium Batteries

Y **, Q He, G Liu, Z Gu, M Wu, T Sun… - Advanced …, 2023 - Wiley Online Library
Abstract The instability of Li10GeP2S12 toward moisture and that toward lithium metal are
two challenges for the application in all‐solid‐state lithium batteries. In this work …

Long-lasting Ni-rich NCMA cathodes via simultaneous microstructural refinement and surface modification

HH Ryu, HW Lim, GC Kang, NY Park… - ACS Energy Letters, 2023 - ACS Publications
Li [Ni1–x–y–z Co x Mn y Al z] O2 (NCMA) cathodes have attracted public attention owing to
their improved durability by leveraging the advantages of NCM and NCA cathodes. As the Ni …

Cathode electrolyte interface engineering by gradient fluorination for high‐performance lithium rich cathode

L Di, C Yufang, S Weiwei, X Wei… - Advanced Energy …, 2023 - Wiley Online Library
Despite their ultrahigh specific capacity, lithium‐rich layered oxide cathodes are still plagued
by challenges such as poor cycle stability and notorious voltage decay, which are primarily …

A disordered rubik's cube‐inspired framework for sodium‐ion batteries with ultralong cycle lifespan

J Peng, B Zhang, W Hua, Y Liang… - Angewandte Chemie …, 2023 - Wiley Online Library
Sodium‐ion batteries (SIBs) with fast‐charge capability and long lifespan could be applied
in various sustainable energy storage systems, from personal devices to grid storage …

A weakly coordinating-intervention strategy for modulating Na+ solvation sheathes and constructing robust interphase in sodium-metal batteries

C Wang, Z Sun, Y Liu, L Liu, X Yin, Q Hou, J Fan… - Nature …, 2024 - nature.com
Constructing powerful anode/cathode interphases by modulate ion solvation structure is the
principle of electrolyte design. However, the methodological and theoretical design …

Additive‐guided Solvation‐regulated Flame‐retardant Electrolyte Enables High‐voltage Lithium Metal Batteries with Robust Electrode Electrolyte Interphases

J Liu, X Li, J Huang, G Yang… - Advanced Functional …, 2024 - Wiley Online Library
Widening the voltage window of the nickel‐rich layered oxide cathode‐based lithium metal
batteries (LMBs) can effectively improve the energy density of rechargeable batteries …

Armor‐like inorganic‐rich cathode electrolyte interphase enabled by the pentafluorophenylboronic acid additive for high‐voltage Li|| NCM622 batteries

Y Yang, H Wang, C Zhu, J Ma - Angewandte Chemie, 2023 - Wiley Online Library
Lithium metal batteries (LMBs) comprising Li metal anode and high‐voltage nickel‐rich
cathode could potentially realize high capacity and power density. However, suitable …

Tuning Interphase Chemistry to Stabilize High‐Voltage LiCoO2 Cathode Material via Spinel Coating

J Liu, J Wang, Y Ni, J Liu, Y Zhang, Y Lu… - Angewandte Chemie …, 2022 - Wiley Online Library
Cathode electrolyte interphases (CEIs) are critical to the cycling stability of high‐voltage
cathodes for batteries, yet their formation mechanism and properties remain elusive. Here …