Chemical flexibility of atomically precise metal clusters

S Li, NN Li, XY Dong, SQ Zang, TCW Mak - Chemical Reviews, 2024 - ACS Publications
Ligand-protected metal clusters possess hybrid properties that seamlessly combine an
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …

Recent developments in the investigation of driving forces for transforming coinage metal nanoclusters

X Zou, X Kang, M Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal nanoclusters serve as an emerging class of modular nanomaterials. The
transformation of metal nanoclusters has been fully reflected in their studies from every …

Platonic and Archimedean solids in discrete metal-containing clusters

XM Luo, YK Li, XY Dong, SQ Zang - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles

I Chakraborty, T Pradeep - Chemical reviews, 2017 - ACS Publications
Atomically precise pieces of matter of nanometer dimensions composed of noble metals are
new categories of materials with many unusual properties. Over 100 molecules of this kind …

Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R **, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Surface coordination chemistry of metal nanomaterials

P Liu, R Qin, G Fu, N Zheng - Journal of the American Chemical …, 2017 - ACS Publications
Surface coordination chemistry of nanomaterials deals with the chemistry on how ligands
are coordinated on their surface metal atoms and influence their properties at the molecular …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Unraveling the long-pursued Au144 structure by x-ray crystallography

N Yan, N **a, L Liao, M Zhu, F **, R **, Z Wu - Science advances, 2018 - science.org
The transition from nanocluster to nanocrystal is a central issue in nanoscience. The atomic
structure determination of metal nanoparticles in the transition size range is challenging and …

[Ag25(SR)18]: The “Golden” Silver Nanoparticle

CP Joshi, MS Bootharaju, MJ Alhilaly… - Journal of the American …, 2015 - ACS Publications
Silver nanoparticles with an atomically precise molecular formula [Ag25 (SR) 18]−(− SR:
thiolate) are synthesized, and their single-crystal structure is determined. This synthesized …

Ag29(BDT)12(TPP)4: A Tetravalent Nanocluster

LG AbdulHalim, MS Bootharaju, Q Tang… - Journal of the …, 2015 - ACS Publications
The bottom-up assembly of nanoparticles into diverse ordered solids is a challenge because
it requires nanoparticles, which are often quasi-spherical, to have interaction anisotropy akin …