Stimulus-controlled anion binding and transport by synthetic receptors

J de Jong, JE Bos, SJ Wezenberg - Chemical Reviews, 2023 - ACS Publications
Anionic species are omnipresent and involved in many important biological processes. A
large number of artificial anion receptors has therefore been developed. Some of these are …

Light-powered dissipative assembly of diazocine coordination cages

H Lee, J Tessarolo, D Langbehn, A Baksi… - Journal of the …, 2022 - ACS Publications
Stimuli-responsive coordination cages allow reversible control over guest binding and
release, relevant for adaptive receptors, carriers, catalysts, and complex systems. Light …

Multiple Azoarenes Based Systems–Photoswitching, Supramolecular Chemistry and Application Prospects

P Kumar, D Gupta, S Grewal, A Srivastava… - The Chemical …, 2022 - Wiley Online Library
In the recent decades, the investigations on photoresponsive molecular systems with
multiple azoarenes are quite popular in diverse perspectives ranging from fundamental …

Light‐Triggered High‐Affinity Binding of Tetramethylammonium over Potassium Ions by [18] crown‐6 in a Tetrahedral Anion Cage

Y Wang, B Li, J Zhu, W Zhang, B Zheng… - Angewandte …, 2022 - Wiley Online Library
An azobenzene‐functionalized bis‐bis (urea) ligand (Lazo) and phosphate anion assemble
to give the first photoactive “aniono” constructs, tetrahedron (A4L6) and helicate (A2L3) …

Photoresponsive Organic Cages─ Computationally Inspired Discovery of Azobenzene-Derived Organic Cages

MC Brand, HG Trowell, JT Pegg… - Journal of the …, 2024 - ACS Publications
The incorporation of photoresponsive groups into porous materials is attractive as it offers
potential advantages in controlling the pore size and selectivity to guest molecules. A …

Stimuli‐Responsive Supramolecular Polymers from Amphiphilic Phosphodiester‐Linked Azobenzene Trimers

O Vybornyi, SX Liu, R Häner - Angewandte Chemie, 2021 - Wiley Online Library
An amphiphilic phosphodiester‐linked azobenzene trimer has been exploited in the
development of stimuli‐responsive, water‐soluble supramolecular polymers. The trimer can …

Fluorescent macrocycle-dye-anchor conjugates for sensing phospholipids in biomembranes

AS Oshchepkov, EC Da Silva, BS Morozov… - Sensors and Actuators B …, 2023 - Elsevier
Negatively charged phospholipids can serve as biomarkers for a number of biological
processes allowing detection of apoptosis in animal cells, drug-induced phospholipidosis as …

Photoresponsive Supramolecular Cages and Macrocycles

E Nieland, J Voss, BM Schmidt - ChemPlusChem, 2023 - Wiley Online Library
The utilisation of light to achieve precise manipulation and control over the structure and
function of supramolecular assemblies has emerged as a highly promising approach in the …

Optimization of atomic density-fitting basis functions for molecular two-electron integral approximations

DN Laikov - The Journal of Chemical Physics, 2020 - pubs.aip.org
A general procedure for the optimization of atomic density-fitting basis functions is designed
with the balance between accuracy and numerical stability in mind. Given one-electron …

Cucurbit [7] uril‐Encapsulation‐Controlled Supramolecular Photoproduct and Radical Fluorescence Emission

M Peng, Y Luo, Y Rao, J Song… - Chemistry–A European …, 2022 - Wiley Online Library
Herein, a host–guest interaction–controlled photoproduct created by using cucurbit [7] uril (Q
[7])‐based pseudorotaxane structures is reported. The assembly exhibited controlled …