The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Reversible electron reservoir feature of redox non-innocent ligand is an important event from
the broader perspectives of metal–ligand cooperativity in catalysis as well as in introducing …

Non-volatile memories will play a decisive role in the next generation of digital technology.
Flash memories are currently the key player in the field, yet they fail to meet the commercial …

Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Electronic symmetry breaking by charge disproportionation results in multifaceted changes
in the electronic, magnetic and optical properties of a material, triggering ferroelectricity …

Herein, we report azo-benzimidazole containing cobalt complexes (1–3) for alcohol
dehydrogenation-triggered C3-alkylation of indoles. In complexes 1–3, ligands are redox …

The new redox-noninnocent azoaromatic pincers 2-(arylazo)-1, 10-phenanthroline (L1) and
2, 9-bis (phenyldiazo)-1, 10-phenanthroline (L2) are reported. The ligand L1 is a tridentate …

It was first reported almost two decades ago that ligands with azo functions are capable of
accepting electron (s) upon coordination to produce azo-anion radical complexes, thereby …

Design of an efficient new catalyst that can mimic the enzymatic pathway for catalytic
dehydrogenation of liquid fuels like alcohols is described in this report. The catalyst is a …

Electroprotic storage materials, though invaluable in energy-related research, are scanty
among non-natural compounds. Herein, we report a zinc (II) complex of the ligand 2, 6-bis …