Hydrogenase enzymes efficiently process H2 and protons at organometallic FeFe, NiFe, or
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …

The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

Energy decomposition analysis (EDA) is an important class of methods to explore the nature
of interaction between fragments in a chemical system. It can decompose the interaction …

Mechanistic investigations of the Ni-catalyzed asymmetric reductive alkenylation of N-
hydroxyphthalimide (NHP) esters and benzylic chlorides are reported. Investigations of the …

The weak interlamellar interaction of covalent organic framework (COF) nanocrystals inhibit
the construction of highly efficient ion/molecular sieving membranes owing to the inferior …

Timely and remote biomarker detection is highly desired in personalized medicine and
health protection but presents great challenges in the devices reported so far. Here, we …

Chemists often use statistical analysis of reaction data with molecular descriptors to identify
structure-reactivity relationships, which can enable prediction and mechanistic …

The construction of carbon–heteroatom bonds is one of the most active areas of research in
organic chemistry because the function of organic molecules is often derived from the …

Dehydrogenative transformations of alkyl chains to alkenes through methylene carbon-
hydrogen (C–H) activation remain a substantial challenge. We report two classes of pyridine …

In modern industries, the aerobic oxidation of C (sp3)-H bonds to achieve the value-added
conversion of hydrocarbons requires high temperatures and pressures, which significantly …