[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Metal–metal bond in lanthanide single-molecule magnets

Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for develo** high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Photochromic crystalline hybrid materials with switchable properties: Recent advances and potential applications

JL Zhao, MH Li, YM Cheng, XW Zhao, Y Xu… - Coordination Chemistry …, 2023 - Elsevier
The search for feasible strategies to construct molecular materials whose physical properties
can be modulated dynamically by external stimuli, especially light for sunlight is the cleanest …

Manipulating on/off single-molecule magnet behavior in a Dy (III)-based photochromic complex

YJ Ma, JX Hu, SD Han, J Pan, JH Li… - Journal of the American …, 2020 - ACS Publications
Exploitation of room temperature (RT) photochromism and photomagnetism to induce single-
molecule magnet (SMM) behavior has potential applications toward optical switches and …

High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium (III) metallocenium single-molecule magnets

KR McClain, CA Gould, K Chakarawet, SJ Teat… - Chemical …, 2018 - pubs.rsc.org
A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications

AG Martynov, Y Horii, K Katoh, Y Bian, J Jiang… - Chemical Society …, 2022 - pubs.rsc.org
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …

A stable pentagonal bipyramidal Dy (III) single-ion magnet with a record magnetization reversal barrier over 1000 K

J Liu, YC Chen, JL Liu, V Vieru, L Ungur… - Journal of the …, 2016 - ACS Publications
Single-molecule magnets (SMMs) with a large spin reversal barrier have been recognized to
exhibit slow magnetic relaxation that can lead to a magnetic hysteresis loop. Synthesis of …

Symmetry-supported magnetic blocking at 20 K in pentagonal bipyramidal Dy (III) single-ion magnets

YC Chen, JL Liu, L Ungur, J Liu, QW Li… - Journal of the …, 2016 - ACS Publications
Single-molecule magnets (SMMs) that can be trapped in one of the bistable magnetic states
separated by an energy barrier are among the most promising candidates for high-density …

Record quantum tunneling time in an air-stable exchange-bias dysprosium macrocycle

Z Zhu, S Paul, C Zhao, J Wu, X Ying… - Journal of the …, 2024 - ACS Publications
In recent years, dysprosium macrocycle single-molecule magnets (SMMs) have received
increasing attention due to their excellent air/thermal stability, strong magnetic anisotropy …