Recent advances in the chemistry of metal carbamates

G Bresciani, L Biancalana, G Pampaloni, F Marchetti - Molecules, 2020 - mdpi.com
Following a related review dating back to 2003, the present review discusses in detail the
various synthetic, structural and reactivity aspects of metal species containing one or more …

Mechanistic investigation of the nickel-catalyzed metathesis between aryl thioethers and aryl nitriles

P Boehm, P Müller, P Finkelstein… - Journal of the …, 2022 - ACS Publications
Functional group metathesis is an emerging field in organic chemistry with promising
synthetic applications. However, no complete mechanistic studies of these reactions have …

Carbon dioxide insertion into group 9 and 10 metal–element σ bonds

N Hazari, JE Heimann - Inorganic Chemistry, 2017 - ACS Publications
Carbon dioxide (CO2) is an appealing feedstock for the sustainable preparation of a variety
of carbon-based commodity chemicals because of its high abundance, low cost, and …

Enhanced catalytic activity of nickel complexes of an adaptive diphosphine–benzophenone ligand in alkyne cyclotrimerization

AF Orsino, M Gutiérrez del Campo, M Lutz… - ACS catalysis, 2019 - ACS Publications
Adaptive ligands, which can adapt their coordination mode to the electronic structure of
various catalytic intermediates, offer the potential to develop improved homogeneous …

Copper-Catalyzed Multicomponent Reactions of Intramolecular and Intermolecular Thiotrifluoromethylation of Alkenes: Access to CF3–Containing 2 …

S Liu, L Jiang - Organic Letters, 2022 - ACS Publications
A copper-catalyzed multicomponent reaction of secondary amines bearing allyl substitution,
isothiocyanates, and Togni reagent II has been developed under Cs2CO3 in DCE at 75° C …

Nickel and Palladium Complexes with Reactive σ‐Metal‐Oxygen Covalent Bonds

LM Martínez‐Prieto, J Cámpora - Israel Journal of Chemistry, 2020 - Wiley Online Library
This article reviews the chemistry of nickel and palladium complexes with terminally bound
hydroxide and alkoxide ligands. The research carried out in our group is discussed in the …

Role of high-spin species and pendant amines in electrocatalytic alcohol oxidation by a nickel phosphine complex

T Gunasekara, Y Tong, AL Speelman, JD Erickson… - ACS …, 2022 - ACS Publications
The development of active and efficient electrocatalysts for oxidation of alcohols using earth-
abundant metals will aid progress toward a renewable energy economy. Here, we present a …

Bis (diisopropylphosphinomethyl) amine Nickel (II) and Nickel (0) Complexes: Coordination Chemistry, Reactivity, and Catalytic Decarbonylative C–H Arylation of …

A Kruckenberg, H Wadepohl, LH Gade - Organometallics, 2013 - ACS Publications
The facile one-step synthesis of five new bis (diisopropylphosphinomethyl) amine ligands
RN (CH2DIP) 2 (DIP= diisopropylphosphine, R= Me–, i Pr–, PhCH2–, 2-ThCH2–, and 2 …

Carbon dioxide activation by “non-nucleophilic” lead alkoxides

ECY Tam, NC Johnstone, L Ferro… - Inorganic …, 2009 - ACS Publications
A series of terminal lead alkoxides have been synthesized utilizing the bulky β-diketiminate
ligand [{N (2, 6-i Pr2C6H3) C (Me)} 2CH]−(BDI). The nucleophilicities of these alkoxides …

Decomposition of Methylnickel (II) Amido, Alkoxo, and Alkyl Complexes by β-Hydrogen Elimination: A Comparative Study

I Matas, J Cámpora, P Palma, E Alvarez - Organometallics, 2009 - ACS Publications
Thermal decomposition of structurally related amido, alkoxo, and alkyl complexes of type [Ni
(Me)(EC (H) RR′)(dippe)](EC (H) RR′= cyclo-NC4H8 (pyrrolidino), N (CH2Ph) 2 …