O‐Heterocycles have been explored in the field of medicinal chemistry for a long time, but
their significance has not been duly recognised and they are often shunned in favour of N …

As a subgroup of heteroatom-substituted alkynes, ynamide has unique structural
characteristics. The alkynyl group of ynamide is activated by the conjugation of nitrogen lone …

With Et3N· 3HF as the fluorinating reagent, a copper (I)-or silver (I)-catalyzed β/α-site-
regiocontrolled trans-hydrofluorination of alkynamides has been achieved, affording the …

A novel and efficient [Cu]-catalyzed one-pot regio-and stereospecific synthesis of benzo [1,
4, 2] dithiazine 1, 1-dioxides and benzo [1, 4, 2] thiaselenazine 1, 1-dioxides by cyclization of …

A copper-catalyzed carboarylation–ring-closure strategy was used for the modular synthesis
of oxazolines via the reaction of 1-aryl-and 1-alkylpropargylamides and diaryliodonium salts …

Two efficient processes based on the iodocyclization of ynamides have been developed:(i)
N-alkynyl tert-butyloxycarbamates were found to undergo a rare 6-exo-dig ring closure …

A metal-free hydrophosphorylation of ynamides with diaryl phosphine oxides has been
developed. A highly E-selective and β-regioselective hydrophosphorylation protocol has …

Based on a halopalladation strategy, we successfully developed a haloesterification
reaction of propargylic amides to synthesize a diverse range of 5-(halomethylene) …

A simple zinc chloride mediated cyclization of ynamidyl N‐carbamates or 2‐ynamidyl‐
(hetero) arylcarboxylates is achieved under mild reaction conditions, leading to the …

2-Oxazolidones are an important class of nitrogen-containing heterocyclic compounds,
which have been found to have a wide range of applications as chiral auxiliaries and …