Diradicals

M Abe - Chemical Reviews, 2013 - ACS Publications
Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …

Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity

R Zhang, Y Wang, Y Zhao, C Redshaw… - Dalton …, 2021 - pubs.rsc.org
α-Diimine ligands, in particular 1, 4-diazabutadiene (dad) and bis (iminoacenaphthene)(
bian) derivatives, have been widely used for coordination with various metals, including …

Synthesis and characterization of first row transition metal complexes containing α-imino alkoxides as precursors for deposition of metal films

CH Winter, LC Kalutarage - US Patent 9,758,866, 2017 - Google Patents
US9758866B2 - Synthesis and characterization of first row transition metal complexes containing
α-imino alkoxides as precursors for deposition of metal films - Google Patents US9758866B2 …

Thermally stable volatile film precursors

CH Winter, TJ Knisley… - US Patent 8,962,876, 2015 - Google Patents
US8962876B2 - Thermally stable volatile film precursors - Google Patents US8962876B2 -
Thermally stable volatile film precursors - Google Patents Thermally stable volatile film …

Neutral bis (α-iminopyridine) metal complexes of the first-row transition ions (Cr, Mn, Fe, Co, Ni, Zn) and their monocationic analogues: mixed valency involving a …

CC Lu, E Bill, T Weyhermüller, E Bothe… - Journal of the …, 2008 - ACS Publications
A series of bis (α-iminopyridine) metal complexes featuring the first-row transition ions (Cr,
Mn, Fe, Co, Ni, and Zn) is presented. It is shown that these ligands are redox noninnocent …

The shortest metal− metal bond yet: molecular and electronic structure of a dinuclear chromium diazadiene complex

KA Kreisel, GPA Yap, O Dmitrenko… - Journal of the …, 2007 - ACS Publications
Reduction of a diazadiene chromium halide complex,[(HLiPr) Cr (μ-Cl)] 2 (1, HLiPr= bis (2, 6-
diisopropylphenyl) diazadiene), with KC8 gave a diamagnetic, bimetallic complex,(HLiPr) …

Complexes of diamagnetic cations with radical anion ligands

IV Ershova, AV Piskunov… - Russian Chemical …, 2020 - iopscience.iop.org
Complexes of diamagnetic cations with radical anion ligands - IOPscience This site uses
cookies. By continuing to use this site you agree to our use of cookies. To find out more, see …

Chemistry of thermally stable bis (amino) silylenes

B Gehrhus, MF Lappert - Journal of Organometallic Chemistry, 2001 - Elsevier
This paper provides a comprehensive review of the chemistry of the thermally stable bis
(amino) silylenes Si [(NCH2But) 2C6H4-1, 2][abbreviated as Si (NN)] 1 and Si [N (But) CH] 2 …

Selective [1, 4]-hydrovinylation of 1, 3-dienes with unactivated olefins enabled by iron diimine catalysts

VA Schmidt, CR Kennedy, MJ Bezdek… - Journal of the American …, 2018 - ACS Publications
The selective, intermolecular [1, 4]-hydrovinylation of conjugated dienes with unactivated α-
olefins catalyzed by α-diimine iron complexes is described. Value-added “skipped” diene …

Reversible switching of organic diradical character via iron-based spin-crossover

A Kawamura, J **e, JN Boyn, KA Jesse… - Journal of the …, 2020 - ACS Publications
Organic diradicals are uncommon species that have been intensely studied for their unique
properties and potential applicability in a diverse range of innovative fields. While there is a …