The importance of second sphere interactions on single molecule magnet performance

BE Matheson, TN Dais, ME Donaldson… - Inorganic Chemistry …, 2023 - pubs.rsc.org
Owing to their potential applications in areas such as information storage, molecular
spintronics, and quantum computing among others; the field of single molecule magnets …

Water-driven reversible switching of single-ion magnetism and proton conduction in a dysprosium sulfonate

D Shao, WJ Tang, Z Ruan, X Yang, L Shi… - Inorganic Chemistry …, 2022 - pubs.rsc.org
We report the design and synthesis of a 1D Dy (III) coordination polymer, comprised of
sulfonate functionalised ligand 8-hydroxyquinoline-5-sulfonic acid (H2SQ) and Dy3+ ions …

Understanding electrostatics and covalency effects in highly anisotropic organometallic sandwich dysprosium complexes [Dy (C m R m) 2](where R= H, SiH 3, CH 3 …

I Tarannum, S Moorthy, SK Singh - Dalton Transactions, 2023 - pubs.rsc.org
In this article, we have thoroughly studied the electronic structure and 4f-ligand covalency of
six mononuclear dysprosium organometallic sandwich complexes [Dy (CmRm) 2] …

Syntheses, Structures, and Magnetic Properties of Novel [3× 1+ 2× 1] Pentanuclear Zinc (II)-Lanthanide (III) Cocrystal Complexes: Slow Magnetic Relaxation Behavior …

S Roy, J Du, EM Manohar, T Aziz, TK Pal… - Crystal Growth & …, 2023 - ACS Publications
A new family of 3d-4f polynuclear cocrystals [LnZn2L2 (CH3CO2) 4]·[Zn2Cl4L]· H2O [where
LnIII= Gd (1), Tb (2), and Dy (3)] are synthesized by the sequential reaction of a tetradentate …

Photocatalytic degradation of dyes and magnetic properties in two one-dimensional coordination polymers

CZ **e, R Luo, Q Gao, X Zhang, DM Zhang, YH Fan… - Polyhedron, 2024 - Elsevier
Two coordination polymers (CPs)[M (HCOO) 2 (TPB)(H 2 O) 2] n (M= Co, 1; Ni, 2; TPB= 1, 3,
5-tri (pyridin-4-yl) benzene) have been successfully synthesized under solvothermal …

Structure and assembly studies of two planar Dy (iii) single molecule magnets with double relaxations

S Yu, L Liu, L Zhou, D Liu, C Chen, HH Zou… - Journal of Materials …, 2024 - pubs.rsc.org
A systematic understanding of the assembly mechanism of single-molecule magnets
(SMMs) is of great significance for the directional synthesis of Dy (III) SMMs as well as …

Unravelling the electronic structure, bonding, and magnetic properties of inorganic dysprosocene analogues [Dy (E 4) 2]−(E= N, P, As, CH)

I Tarannum, SK Singh - Physical Chemistry Chemical Physics, 2025 - pubs.rsc.org
Organometallic sandwich complexes of Dy (III) ion are ubiquitous for designing high-
temperature single-ion magnets with blocking temperatures close to the liquid nitrogen …

Mononuclear Lanthanide Complexes in Triangular Dodecahedron Geometry: Manifestation of Single Ion Magnet Behavior for DyIII Analogue

S Roy, J Du, EM Manohar, L Sun, N Ahmed… - Crystal Growth & …, 2023 - ACS Publications
In this work, a tridentate N, N, O ligand [(E)-4-nitro-2-((pyridine-2-ylmethylene) amino)
phenol](LNO2H) is employed for the synthesis of neutral structurally similar complexes [DyIII …