Magnetic lanthanide (Ln) metal complexes exhibiting magnetic bistability can behave as
molecular nanomagnets, also known as single-molecule magnets (SMMs), suitable for …

Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

The elucidation of geometries is the fundamental to further investigate and develop fullerene
chemistry, an epoch-making discipline since 1985. Although the geometries of fullerenes …

Conspectus Concrete crystallographic results of endohedral metallofullerenes (EMFs)
disclose that the bonding within the metallic clusters and the interactions between the metal …

Although most of the M2C2 n-type metallofullerenes (EMFs) tend to form carbide cluster
EMFs, we report herein that Lu-containing EMFs Lu2C2 n (2 n= 82, 84, 86) are actually …

Comprehensive Summary The hollow cavity of fullerenes is an ideal host for the stabilization
of a variety of otherwise unstable metallic clusters, enabling the discovery of novel …

Endohedral metallofullerenes (EMFs), namely fullerenes with metallic species encapsulated
inside, represent an ideal platform to investigate metal–metal or metal–carbon interactions …

Direct yttrium–yttrium bonding has been a long-sought puzzle in organometallic chemistry to
understand the catalytic processes that involve yttrium. Herein, we report the first …

Novel actinide cluster fullerenes, U2C2@ I h (7)-C80 and U2C2@ D 3 h (5)-C78, were
synthesized and fully characterized by mass spectrometry, single-crystal X-ray …

The successful isolation and unambiguous crystallographic assignment of a series of
lutetium-containing endohedral metallofullerenes (EMFs), Lu2C2n (2n= 76, 78, 80, 84, 86 …