Recent advances in heterocyclic nanographenes and other polycyclic heteroaromatic compounds
A Borissov, YK Maurya, L Moshniaha… - Chemical …, 2021 - ACS Publications
This review surveys recent progress in the chemistry of polycyclic heteroaromatic molecules
with a focus on structural diversity and synthetic methodology. The article covers literature …
with a focus on structural diversity and synthetic methodology. The article covers literature …
Stereoelectronic power of oxygen in control of chemical reactivity: the anomeric effect is not alone
Although carbon is the central element of organic chemistry, oxygen is the central element of
stereoelectronic control in organic chemistry. Generally, a molecule with a C–O bond has …
stereoelectronic control in organic chemistry. Generally, a molecule with a C–O bond has …
Alkali‐Metal Mediation: Diversity of Applications in Main‐Group Organometallic Chemistry
TX Gentner, RE Mulvey - Angewandte Chemie International …, 2021 - Wiley Online Library
Organolithium compounds have been at the forefront of synthetic chemistry for over a
century, as they mediate the synthesis of myriads of compounds that are utilised worldwide …
century, as they mediate the synthesis of myriads of compounds that are utilised worldwide …
Enantioconvergent amination of racemic tertiary C–H bonds
Racemization is considered to be an intrinsic stereochemical feature of free radical
chemistry as can be seen in traditional radical halogenation reactions of optically active …
chemistry as can be seen in traditional radical halogenation reactions of optically active …
Enantioselective radical construction of 5-membered cyclic sulfonamides by metalloradical C–H amination
Both arylsulfonyl and alkylsulfonyl azides can be effectively activated by the cobalt (II)
complexes of D 2-symmetric chiral amidoporphyrins for enantioselective radical 1, 5-C–H …
complexes of D 2-symmetric chiral amidoporphyrins for enantioselective radical 1, 5-C–H …
Transition metal-catalyzed sp 3 C–H activation and intramolecular C–N coupling to construct nitrogen heterocyclic scaffolds
M Zhang, Q Wang, Y Peng, Z Chen, C Wan… - Chemical …, 2019 - pubs.rsc.org
Nitrogen heterocycles are of great medicinal importance, and the construction of nitrogen
heterocyclic scaffolds has been one of the focuses in synthetic organic chemistry. Recently …
heterocyclic scaffolds has been one of the focuses in synthetic organic chemistry. Recently …
Selectivity control in thiol–yne click reactions via visible light induced associative electron upconversion
An associative electron upconversion is proposed as a key step determining the selectivity
of thiol–yne coupling. The developed synthetic approach provided an efficient tool to access …
of thiol–yne coupling. The developed synthetic approach provided an efficient tool to access …
Metal-free and additive-free synthesis of imides and nitriles from ketones via oxidative cleavage of C (O)–C bonds
The development of metal-free catalytic systems is highly desirable in organic
transformation. Herein, a biomass-derived carbon catalyst with a high surface area was …
transformation. Herein, a biomass-derived carbon catalyst with a high surface area was …
Hole Catalysis of Cycloaddition Reactions: How to Activate and Control Oxidant Upconversion in Radical-Cationic Diels–Alder Reactions
In order to use holes as catalysts, the oxidized product should be able to transfer the hole to
a fresh reactant. For that, the hole-catalyzed reaction must increase the oxidation potential …
a fresh reactant. For that, the hole-catalyzed reaction must increase the oxidation potential …
Dynamic response and discrimination of gaseous sarin using a boron‐difluoride complex film‐based fluorescence sensor
This study presents a novel boron‐difluoride complex‐based fluorescent nanofilm sensor
capable of detecting sarin vapors in the environment by reporting an output fluorescence …
capable of detecting sarin vapors in the environment by reporting an output fluorescence …