Manipulating matter by strong coupling to vacuum fields
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …
(cQED) is the so-called strong coupling regime, which appears when the interaction …
Plasmonic coupling architectures for enhanced photocatalysis
Plasmonic photocatalysis is a promising approach for solar energy transformation.
Comparing with isolated metal nanoparticles, the plasmonic coupling architectures can …
Comparing with isolated metal nanoparticles, the plasmonic coupling architectures can …
Electric-field mediated chemistry: uncovering and exploiting the potential of (oriented) electric fields to exert chemical catalysis and reaction control
This Perspective discusses oriented external-electric-fields (OEEF), and other electric-field
types, as “smart reagents”, which enable in principle control over wide-ranging aspects of …
types, as “smart reagents”, which enable in principle control over wide-ranging aspects of …
Molecular polaritons for controlling chemistry with quantum optics
This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic
physical principles and consequences of strong light–matter coupling common to molecular …
physical principles and consequences of strong light–matter coupling common to molecular …
Cavity catalysis by cooperative vibrational strong coupling of reactant and solvent molecules
Here, we report the catalytic effect of vibrational strong coupling (VSC) on the solvolysis of
para‐nitrophenyl acetate (PNPA), which increases the reaction rate by an order of …
para‐nitrophenyl acetate (PNPA), which increases the reaction rate by an order of …
Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
Coupled cluster theory for molecular polaritons: Changing ground and excited states
We present an ab initio correlated approach to study molecules that interact strongly with
quantum fields in an optical cavity. Quantum electrodynamics coupled cluster theory …
quantum fields in an optical cavity. Quantum electrodynamics coupled cluster theory …
Quantum effects in chemical reactions under polaritonic vibrational strong coupling
The electromagnetic field in an optical cavity can dramatically modify and even control
chemical reactivity via vibrational strong coupling (VSC). Since the typical vibration and …
chemical reactivity via vibrational strong coupling (VSC). Since the typical vibration and …
Relevance of the quadratic diamagnetic and self-polarization terms in cavity quantum electrodynamics
Experiments at the interface of quantum optics and chemistry have revealed that strong
coupling between light and matter can substantially modify the chemical and physical …
coupling between light and matter can substantially modify the chemical and physical …
Cavity Casimir-Polder forces and their effects in ground-state chemical reactivity
Here, we present a fundamental study on how the ground-state chemical reactivity of a
single molecule can be modified in a QED scenario, ie, when it is placed inside a nanoscale …
single molecule can be modified in a QED scenario, ie, when it is placed inside a nanoscale …