Manipulating matter by strong coupling to vacuum fields

FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …

Plasmonic coupling architectures for enhanced photocatalysis

D Liu, C Xue - Advanced Materials, 2021 - Wiley Online Library
Plasmonic photocatalysis is a promising approach for solar energy transformation.
Comparing with isolated metal nanoparticles, the plasmonic coupling architectures can …

Electric-field mediated chemistry: uncovering and exploiting the potential of (oriented) electric fields to exert chemical catalysis and reaction control

S Shaik, D Danovich, J Joy, Z Wang… - Journal of the American …, 2020 - ACS Publications
This Perspective discusses oriented external-electric-fields (OEEF), and other electric-field
types, as “smart reagents”, which enable in principle control over wide-ranging aspects of …

Molecular polaritons for controlling chemistry with quantum optics

F Herrera, J Owrutsky - The Journal of chemical physics, 2020 - pubs.aip.org
This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic
physical principles and consequences of strong light–matter coupling common to molecular …

Cavity catalysis by cooperative vibrational strong coupling of reactant and solvent molecules

J Lather, P Bhatt, A Thomas… - Angewandte Chemie …, 2019 - Wiley Online Library
Here, we report the catalytic effect of vibrational strong coupling (VSC) on the solvolysis of
para‐nitrophenyl acetate (PNPA), which increases the reaction rate by an order of …

Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry

JA Campos-Gonzalez-Angulo, YR Poh, M Du… - The Journal of …, 2023 - pubs.aip.org
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …

Coupled cluster theory for molecular polaritons: Changing ground and excited states

TS Haugland, E Ronca, EF Kjønstad, A Rubio, H Koch - Physical Review X, 2020 - APS
We present an ab initio correlated approach to study molecules that interact strongly with
quantum fields in an optical cavity. Quantum electrodynamics coupled cluster theory …

Quantum effects in chemical reactions under polaritonic vibrational strong coupling

PY Yang, J Cao - The Journal of Physical Chemistry Letters, 2021 - ACS Publications
The electromagnetic field in an optical cavity can dramatically modify and even control
chemical reactivity via vibrational strong coupling (VSC). Since the typical vibration and …

Relevance of the quadratic diamagnetic and self-polarization terms in cavity quantum electrodynamics

C Schäfer, M Ruggenthaler, V Rokaj, A Rubio - ACS photonics, 2020 - ACS Publications
Experiments at the interface of quantum optics and chemistry have revealed that strong
coupling between light and matter can substantially modify the chemical and physical …

Cavity Casimir-Polder forces and their effects in ground-state chemical reactivity

J Galego, C Climent, FJ Garcia-Vidal, J Feist - Physical Review X, 2019 - APS
Here, we present a fundamental study on how the ground-state chemical reactivity of a
single molecule can be modified in a QED scenario, ie, when it is placed inside a nanoscale …