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Molecular catalysis of electrochemical reactions. Mechanistic aspects
JM Savéant - Chemical Reviews, 2008 - ACS Publications
Electrochemical reactions often require an important overpotential1 to proceed at an
appreciable rate. This is particularly true when the reaction does not merely consist of an …
appreciable rate. This is particularly true when the reaction does not merely consist of an …
Kinetics and mechanism of the dissociative reduction of C X and X X bonds (X O, S)
F Maran, DDM Wayner, MS Workentin - 2001 - Elsevier
Publisher Summary This chapter discusses some recent developments and methodologies
that have impacted the understanding of dissociative electron transfer (ET). It focuses on the …
that have impacted the understanding of dissociative electron transfer (ET). It focuses on the …
Electroreduction of Dialkyl Peroxides. Activation−Driving Force Relationships and Bond Dissociation Free Energies1a
The electrochemical reduction of five dialkyl peroxides in DMF was studied by cyclic
voltammetry. The electron transfer (ET) to the selected compounds is concerted with the …
voltammetry. The electron transfer (ET) to the selected compounds is concerted with the …
Organosulfur monolayers at gold surfaces: reexamination of the case for sulfide adsorption and implications to the formation of monolayers from thiols and disulfides
This paper presents the results from a reexamination of the adsorption of organosulfides on
gold films. Our original goal was to explore the adsorption of different organosulfur …
gold films. Our original goal was to explore the adsorption of different organosulfur …
The role and relevance of the transfer coefficient α in the study of dissociative electron transfers: concepts and examples from the electroreduction of perbenzoates
S Antonello, F Maran - Journal of the American Chemical Society, 1999 - ACS Publications
The electrochemical transfer coefficient α is shown to be a sensitive probe of the mechanism
by which electron transfer and bond cleavage may be coupled in dissociative electron …
by which electron transfer and bond cleavage may be coupled in dissociative electron …
Theoretical and electrochemical analysis of dissociative electron transfers proceeding through formation of loose radical anion species: reduction of symmetrical and …
S Antonello, R Benassi, G Gavioli… - Journal of the …, 2002 - ACS Publications
The dissociative reduction of a series of symmetrical (RSSR, R= H, Me, t-Bu, Ph) and
unsymmetrical disulfides (RSSR ', R= H, R '= Me and R= Ph, R '= Me, t-Bu) was studied …
unsymmetrical disulfides (RSSR ', R= H, R '= Me and R= Ph, R '= Me, t-Bu) was studied …
Kinetics of the Reduction of Dialkyl Peroxides. New Insights into the Dynamics of Dissociative Electron Transfer1
RL Donkers, F Maran, DDM Wayner… - Journal of the …, 1999 - ACS Publications
The concerted dissociative reduction of di-tert-butyl peroxide (DTBP), dicumyl peroxide
(DCP), and di-n-butyl peroxide (DNBP) is evaluated by both heterogeneous and …
(DCP), and di-n-butyl peroxide (DNBP) is evaluated by both heterogeneous and …
Evidence for the Transition between Concerted and Stepwise Heterogeneous Electron Transfer− Bond Fragmentation Mechanisms
S Antonello, F Maran - Journal of the American Chemical Society, 1997 - ACS Publications
The electrochemical reduction of tert-butyl p-cyanoperbenzoate in DMF leads to the
cleavage of the oxygen− oxygen bond. A subsequent reaction yielding tert-butyl p …
cleavage of the oxygen− oxygen bond. A subsequent reaction yielding tert-butyl p …
Homogeneous Reduction of Haloacetonitriles by Electrogenerated Aromatic Radical Anions: Determination of the Reduction Potential of •CH2CN
AA Isse, A Gennaro - The Journal of Physical Chemistry A, 2004 - ACS Publications
The mechanism of homogeneous reduction of XCH2CN (X= Cl, Br, I) by organic radical
anions (D•-) has been investigated in DMF. All three haloacetonitriles undergo a concerted …
anions (D•-) has been investigated in DMF. All three haloacetonitriles undergo a concerted …
Double‐Layer Correction for Electron‐Transfer Kinetics at Glassy Carbon and Mercury Electrodes in N,N‐Dimethylformamide
A Belèn Meneses, S Antonello… - … Journal Devoted to …, 2006 - Wiley Online Library
The double‐layer properties of the glassy carbon electrode in N, N‐dimethylformamide
(DMF) containing tetrabutylammonium perchlorate (TBAP) at different concentrations have …
(DMF) containing tetrabutylammonium perchlorate (TBAP) at different concentrations have …