Present and future of surface-enhanced Raman scattering

J Langer, D Jimenez de Aberasturi, J Aizpurua… - ACS …, 2019 - ACS Publications
The discovery of the enhancement of Raman scattering by molecules adsorbed on
nanostructured metal surfaces is a landmark in the history of spectroscopic and analytical …

Cucurbiturils‐mediated noble metal nanoparticles for applications in sensing, sers, theranostics, and catalysis

LL Tan, M Wei, L Shang… - Advanced Functional …, 2021 - Wiley Online Library
Noble metal nanoparticles (NMNPs), which spring up like mushrooms, are gaining
momentum owing to their unique physicochemical characteristics. Cucurbiturils, a class of …

Thermal effects–an alternative mechanism for plasmon-assisted photocatalysis

Y Dubi, IW Un, Y Sivan - Chemical Science, 2020 - pubs.rsc.org
Recent experiments claimed that the catalysis of reaction rates in numerous bond-
dissociation reactions occurs via the decrease of activation barriers driven by non …

The fast and the furious: Ultrafast hot electrons in plasmonic metastructures. Size and structure matter

LV Besteiro, P Yu, Z Wang, AW Holleitner, GV Hartland… - Nano Today, 2019 - Elsevier
This review focuses on the generation of energetic (hot) electrons in plasmonic
metastructures and nanomaterials, and their characterization through time-resolved …

Investigation of the mechanisms of plasmon-mediated photocatalysis: synergistic contribution of near-field and charge transfer effects

Z Fusco, K Catchpole, FJ Beck - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
Plasmonic photocatalysis is an attractive way to drive and enhance chemical reactions. The
relative importance of thermal and non-thermal effects in driving the reaction is still under …

Recent developments in plasmon-assisted photocatalysis—A personal Perspective

Y Sivan, Y Dubi - Applied Physics Letters, 2020 - pubs.aip.org
It has been known for many years that metallic nanoparticles can catalyze various chemical
reactions, both in the dark and under illumination, through different mechanisms. In the last …

The role of heat generation and fluid flow in plasmon-enhanced reduction–oxidation reactions

IW Un, Y Sivan - ACS Photonics, 2021 - ACS Publications
Recently, we have shown that thermal effects play a crucial role in speeding up the rate of
bond-dissociation reactions. This was done by applying a simple temperature-shifted …

Tracking interfacial single-molecule pH and binding dynamics via vibrational spectroscopy

J Huang, DB Grys, J Griffiths, B de Nijs, M Kamp… - Science …, 2021 - science.org
Understanding single-molecule chemical dynamics of surface ligands is of critical
importance to reveal their individual pathways and, hence, roles in catalysis, which …

Hot electron science in plasmonics and catalysis: what we argue about

JJ Baumberg - Faraday Discussions, 2019 - pubs.rsc.org
Hot electron photochemistry has made strong claims for improved control of chemical
reactions. Here I discuss these claims in the light of a plethora of model experiments and …

Disentangling Plasmonic Enhancement of Electronic and Thermal Effects in Catalysis Using In Operando X-ray Diffraction

R Miyar, IW Un, S Har Lavan, Y Dubi, JH Baraban… - ACS …, 2025 - ACS Publications
Photocatalysis by illumination of plasmonic catalytic nanostructures may offer energetically
efficient and highly selective alternatives to state-of-the-art thermocatalysis, which typically …