Present and future of surface-enhanced Raman scattering
The discovery of the enhancement of Raman scattering by molecules adsorbed on
nanostructured metal surfaces is a landmark in the history of spectroscopic and analytical …
nanostructured metal surfaces is a landmark in the history of spectroscopic and analytical …
Cucurbiturils‐mediated noble metal nanoparticles for applications in sensing, sers, theranostics, and catalysis
LL Tan, M Wei, L Shang… - Advanced Functional …, 2021 - Wiley Online Library
Noble metal nanoparticles (NMNPs), which spring up like mushrooms, are gaining
momentum owing to their unique physicochemical characteristics. Cucurbiturils, a class of …
momentum owing to their unique physicochemical characteristics. Cucurbiturils, a class of …
Thermal effects–an alternative mechanism for plasmon-assisted photocatalysis
Recent experiments claimed that the catalysis of reaction rates in numerous bond-
dissociation reactions occurs via the decrease of activation barriers driven by non …
dissociation reactions occurs via the decrease of activation barriers driven by non …
The fast and the furious: Ultrafast hot electrons in plasmonic metastructures. Size and structure matter
This review focuses on the generation of energetic (hot) electrons in plasmonic
metastructures and nanomaterials, and their characterization through time-resolved …
metastructures and nanomaterials, and their characterization through time-resolved …
Investigation of the mechanisms of plasmon-mediated photocatalysis: synergistic contribution of near-field and charge transfer effects
Plasmonic photocatalysis is an attractive way to drive and enhance chemical reactions. The
relative importance of thermal and non-thermal effects in driving the reaction is still under …
relative importance of thermal and non-thermal effects in driving the reaction is still under …
Recent developments in plasmon-assisted photocatalysis—A personal Perspective
It has been known for many years that metallic nanoparticles can catalyze various chemical
reactions, both in the dark and under illumination, through different mechanisms. In the last …
reactions, both in the dark and under illumination, through different mechanisms. In the last …
The role of heat generation and fluid flow in plasmon-enhanced reduction–oxidation reactions
Recently, we have shown that thermal effects play a crucial role in speeding up the rate of
bond-dissociation reactions. This was done by applying a simple temperature-shifted …
bond-dissociation reactions. This was done by applying a simple temperature-shifted …
Tracking interfacial single-molecule pH and binding dynamics via vibrational spectroscopy
Understanding single-molecule chemical dynamics of surface ligands is of critical
importance to reveal their individual pathways and, hence, roles in catalysis, which …
importance to reveal their individual pathways and, hence, roles in catalysis, which …
Hot electron science in plasmonics and catalysis: what we argue about
JJ Baumberg - Faraday Discussions, 2019 - pubs.rsc.org
Hot electron photochemistry has made strong claims for improved control of chemical
reactions. Here I discuss these claims in the light of a plethora of model experiments and …
reactions. Here I discuss these claims in the light of a plethora of model experiments and …
Disentangling Plasmonic Enhancement of Electronic and Thermal Effects in Catalysis Using In Operando X-ray Diffraction
Photocatalysis by illumination of plasmonic catalytic nanostructures may offer energetically
efficient and highly selective alternatives to state-of-the-art thermocatalysis, which typically …
efficient and highly selective alternatives to state-of-the-art thermocatalysis, which typically …