Molecular hydrogen (H2) is considered an ideal energy vector and a clean fuel, due to its
zero-carbon combustion. Nevertheless, despite hydrogen is the most and one of the most …

Oxidative methane (CH4) carbonylation promises a direct route to the synthesis of value-
added oxygenates such as acetic acid (CH3COOH). Here, we report a strategy to realize …

Molecular Ir catalysts have emerged as an important class of model catalysts for
understanding structure–activity relationships in water oxidation, a reaction that is central to …

The cobalt–phosphate amorphous oxyhydroxide water-splitting catalyst, CoPi, is widely
investigated because of its reactivity and self-repair analogous to the oxygen-evolving …

A combination of the exceptional stability of fac-[Ir (H2O) 3 (NO2) 3] together with
thermolability of nitro and aqua ligands and high solubility in various solvents makes it …

Increased demand for a carbon-neutral sustainable energy scheme augmented by climatic
threats motivates the design and exploration of novel approaches that reserve intermittent …

The molecular nature and the structure of the real catalyst are matters of serious concern in
homogeneous catalysis. Catalyst transformation in molecular water oxidation catalysis …

The present article deals with the structurally and spectroelectrochemically characterized
newer class of ruthenium-azoheteroarenes [RuII (Ph-trpy)(Cl)(L)] ClO4,[1] ClO4–[3] ClO4 (Ph …

Multinuclear molecular catalysts mimicking natural photosynthesis have been shown to
facilitate water oxidation; however, such catalysts typically operate in organic solutions …

A stringent comparison between two pairs of molecular/immobilized water oxidation
catalysts ([Cp* Ir (Me‐pica) Cl], 1, versus 1_SiO2, Me‐pica= κ2‐N‐methyl‐picolinamide;[Cp …