Designing artificial metalloenzymes by tuning of the environment beyond the primary coordination sphere

C Van Stappen, Y Deng, Y Liu, H Heidari… - Chemical …, 2022 - ACS Publications
Metalloenzymes catalyze a variety of reactions using a limited number of natural amino
acids and metallocofactors. Therefore, the environment beyond the primary coordination …

Copper active sites in biology

EI Solomon, DE Heppner, EM Johnston… - Chemical …, 2014 - ACS Publications
On the basis of its generally accessible I/II redox couple and bioavailability, copper plays a
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …

Kupferkatalysierte aerobe oxidative C‐H‐Funktionalisierungen: Trends und Erkenntnisse zum Mechanismus

AE Wendlandt, AM Suess, SS Stahl - Angewandte Chemie, 2011 - Wiley Online Library
Die selektive Oxidation von C‐H‐Bindungen und der Einsatz von O2 als stöchiometrisches
Oxidationsmittel stellen zwei wesentliche Herausforderungen in der organischen Chemie …

Palladiumoxidasekatalyse: selektive Oxidation durch direkte disauerstoffgekoppelte Umsetzung

SS Stahl - Angewandte Chemie, 2004 - Wiley Online Library
Die selektive aerobe Oxidation organischer Verbindungen ist eines der fundamentalsten
Probleme der modernen organischen Chemie. Effektive Lösungen müssen die spezifische …

Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH3-Mediated Selective Catalytic …

C Negri, T Selleri, E Borfecchia, A Martini… - Journal of the …, 2020 - ACS Publications
The NH3-mediated selective catalytic reduction (NH3-SCR) of NOx over Cu-ion-exchanged
chabazite (Cu-CHA) catalysts is the basis of the technology for abatement of NOx from …

Towards improving H2S catalytic oxidation on porous carbon materials at room temperature: A review of governing and influencing factors, recent advances …

C Yang, Y Wang, M Liang, Z Su, X Liu, H Fan… - Applied Catalysis B …, 2023 - Elsevier
Given that H 2 S detrimentally affects various aspects of human life including an
environment, health, industrial infrastructure and catalytic processes, its removal from …

O2 Reduction in Enzymatic Biofuel Cells

N Mano, A de Poulpiquet - Chemical reviews, 2017 - ACS Publications
Catalytic four-electron reduction of O2 to water is one of the most extensively studied
electrochemical reactions due to O2 exceptional availability and high O2/H2O redox …

Theory of multiple proton–electron transfer reactions and its implications for electrocatalysis

MTM Koper - Chemical science, 2013 - pubs.rsc.org
This perspective article outlines a simple but general theoretical analysis for multiple proton–
electron transfer reactions, based on the microscopic theory of proton-coupled electron …

Fungal laccases–occurrence and properties

P Baldrian - FEMS microbiology reviews, 2006 - academic.oup.com
Laccases of fungi attract considerable attention due to their possible involvement in the
transformation of a wide variety of phenolic compounds including the polymeric lignin and …

Biologically inspired oxidation catalysis

L Que Jr, WB Tolman - Nature, 2008 - nature.com
The development of processes for selective hydrocarbon oxidation is a goal that has long
been pursued. An additional challenge is to make such processes environmentally friendly …