Metal–organic cages (MOCs) are discrete, supramolecular entities that consist of metal
nodes and organic linkers, which can offer solution processability and high porosity …

Conspectus Coordination-driven self-assembly can produce large, symmetrical, hollow
cages that are synthetically easy to access. The functions provided by these aesthetically …

Conspectus The field of supramolecular chemistry has its foundation in molecular
recognition and selective binding of guest molecules, often with remarkably strong binding …

The expression of biological functions, such as enzyme catalysis, immune response, and
cargo transport in confined nanospaces, with very different physical and chemical …

Oriented external electric fields (OEEFs) offer a unique chance to tune catalytic selectivity by
orienting the alignment of the electric field along the axis of the activated bond for a specific …

Metal–organic polyhedra featuring non-Archimedean/Platonic architectures with multiple
kinds of vertices have aroused great attention for their fascinating structures and properties …

A look at the elegance and efficiency of biological machines readily reveals that Nature
masters the full gamut of chemical interactions to compose masterpieces of the living world …

Post‐synthetic modification (PSM) is an effective approach for the tailored functionalization
of metal‐organic architectures, but its generalizability remains challenging. Herein we report …

Metal–organic cages (MOCs) are discrete molecular assemblies formed by coordination
bonds between metal nodes and organic ligands. The application of MOCs has been greatly …

Nanospaces are ubiquitous in the realm of biological systems and are of significant interest
among supramolecular chemists. Understanding chemical behavior within nanospaces …