Dimeric magnesium(I) β-diketiminates: a new class of quasi-universal reducing agent
C Jones - Nature Reviews Chemistry, 2017 - nature.com
Since the first report of their isolation in 2007, magnesium (i) dimers have transitioned from
being chemical curiosities to versatile reducing agents that are used by an ever-increasing …
being chemical curiosities to versatile reducing agents that are used by an ever-increasing …
Topological analysis of the metal-metal bond: A tutorial review
C Lepetit, P Fau, K Fajerwerg, ML Kahn… - Coordination Chemistry …, 2017 - Elsevier
This contribution explains how the topological methods of analysis of the electron density
and related functions such as the electron localization function (ELF) and the electron …
and related functions such as the electron localization function (ELF) and the electron …
Strongly reducing magnesium (0) complexes
B Rösch, TX Gentner, J Eyselein, J Langer, H Elsen… - Nature, 2021 - nature.com
A complex of a metal in its zero oxidation state can be considered a stabilized, but highly
reactive, form of a single metal atom. Such complexes are common for the more noble …
reactive, form of a single metal atom. Such complexes are common for the more noble …
Probing the extremes of covalency in M− Al bonds: lithium and zinc aluminyl compounds
Synthetic routes to lithium, magnesium, and zinc aluminyl complexes are reported, allowing
for the first structural characterization of an unsupported lithium–aluminium bond …
for the first structural characterization of an unsupported lithium–aluminium bond …
CaY@C2n: Exploring Molecular Qubits with Ca–Y Metal–Metal Bonds
J Qiu, L Abella, X Du, Z Cao, Z He… - Journal of the …, 2024 - ACS Publications
Metal–metal bonding is crucial in chemistry for advancing our understanding of the
fundamental aspects of chemical bonds. Metal–metal bonds based on alkaline-earth (Ae) …
fundamental aspects of chemical bonds. Metal–metal bonds based on alkaline-earth (Ae) …
On the nature and limits of alkaline earth–triel bonding
JT Boronski, LP Griffin, C Conder, AE Crumpton… - Chemical …, 2024 - pubs.rsc.org
The synthesis of a series of isostructural organometallic complexes featuring Ae–Tr bonds
(Ae= Be, Mg; Tr= Al, Ga, In) has been investigated, and their electronic structures probed by …
(Ae= Be, Mg; Tr= Al, Ga, In) has been investigated, and their electronic structures probed by …
Highly active superbulky alkaline earth metal amide catalysts for hydrogenation of challenging alkenes and aromatic rings
J Martin, C Knüpfer, J Eyselein, C Färber… - Angewandte …, 2020 - Wiley Online Library
Two series of bulky alkaline earth (Ae) metal amide complexes have been prepared: Ae [N
(TRIP) 2] 2 (1‐Ae) and Ae [N (TRIP)(DIPP)] 2 (2‐Ae)(Ae= Mg, Ca, Sr, Ba; TRIP= SiiPr3 …
(TRIP) 2] 2 (1‐Ae) and Ae [N (TRIP)(DIPP)] 2 (2‐Ae)(Ae= Mg, Ca, Sr, Ba; TRIP= SiiPr3 …
A neutral beryllium (I) radical
A Neutral Beryllium(I) Radical - Czernetzki - 2021 - Angewandte Chemie International Edition -
Wiley Online Library Skip to Article Content Skip to Article Information Wiley Online Library …
Wiley Online Library Skip to Article Content Skip to Article Information Wiley Online Library …
A Planar Nickelaspiropentane Complex with Magnesium-Based Metalloligands: Synthesis, Structure, and Synergistic Dihydrogen Activation
Y Cai, S Jiang, T Rajeshkumar… - Journal of the American …, 2022 - ACS Publications
The nature of transition-metal–olefin bonding has been explained by the Dewar–Chatt–
Duncanson model within a continuum of two extremes, namely, a π-complex and a …
Duncanson model within a continuum of two extremes, namely, a π-complex and a …
A combined experimental and computational study on the reaction of fluoroarenes with Mg–Mg, Mg–Zn, Mg–Al and Al–Zn bonds
Through a combined experimental and computational (DFT) approach, the reaction
mechanism of the addition of fluoroarenes to Mg–Mg bonds has been determined as a …
mechanism of the addition of fluoroarenes to Mg–Mg bonds has been determined as a …