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Deciphering photoinduced catalytic reaction mechanisms in natural and artificial photosynthetic systems on multiple temporal and spatial scales using X-ray probes
Utilization of renewable energies for catalytically generating value-added chemicals is
highly desirable in this era of rising energy demands and climate change impacts. Artificial …
highly desirable in this era of rising energy demands and climate change impacts. Artificial …
[HTML][HTML] Charge migration and charge transfer in molecular systems
The transfer of charge at the molecular level plays a fundamental role in many areas of
chemistry, physics, biology and materials science. Today, more than 60 years after the …
chemistry, physics, biology and materials science. Today, more than 60 years after the …
Femtosecond x-ray spectroscopy of an electrocyclic ring-opening reaction
The ultrafast light-activated electrocyclic ring-opening reaction of 1, 3-cyclohexadiene is a
fundamental prototype of photochemical pericyclic reactions. Generally, these reactions are …
fundamental prototype of photochemical pericyclic reactions. Generally, these reactions are …
Near-Infrared-to-Visible Photon Upconversion Sensitized by a Metal Complex with Spin-Forbidden yet Strong S0–T1 Absorption
Near-infrared (NIR)-to-visible (vis) photon upconversion (UC) is useful for various
applications; however, it remains challenging in triplet–triplet annihilation-based UC, mainly …
applications; however, it remains challenging in triplet–triplet annihilation-based UC, mainly …
Tracking multiple components of a nuclear wavepacket in photoexcited Cu (I)-phenanthroline complex using ultrafast X-ray spectroscopy
Disentangling the strong interplay between electronic and nuclear degrees of freedom is
essential to achieve a full understanding of excited state processes during ultrafast …
essential to achieve a full understanding of excited state processes during ultrafast …
Dynamic surface reconstruction unifies the electrocatalytic oxygen evolution performance of nonstoichiometric mixed metal oxides
Compositionally versatile, nonstoichiometric, mixed ionic–electronic conducting metal
oxides of the form A n+ 1B n O3 n+ 1 (n= 1→∞; A= rare-earth-/alkaline-earth-metal cation; …
oxides of the form A n+ 1B n O3 n+ 1 (n= 1→∞; A= rare-earth-/alkaline-earth-metal cation; …
Ultrafast X-ray photochemistry at European XFEL: capabilities of the femtosecond X-ray experiments (FXE) instrument
Featured Application Femtosecond X-ray Experiments on photoexcited chemical systems
deliver a portfolio of new observables including electronic, spin and nuclear dynamics. This …
deliver a portfolio of new observables including electronic, spin and nuclear dynamics. This …
Spectroscopic Techniques to Unravel Mechanistic Details in Light‐Induced Transformations and Photoredox Catalysis
The rapid development of photo (redox) catalysis within the last decades is remarkable to
the extent that the utilization of light‐driven processes in organic chemistry has become a …
the extent that the utilization of light‐driven processes in organic chemistry has become a …
Excited-State Charge Distribution of a Donor− π–Acceptor Zn Porphyrin Probed by N K-Edge Transient Absorption Spectroscopy
Zinc porphyrin solar cell dyes with donor− π–acceptor architectures combine light absorber
(π), electron-donor, and electron-acceptor moieties inside a single molecule with atomic …
(π), electron-donor, and electron-acceptor moieties inside a single molecule with atomic …
Theoretical rationalization of the emission properties of prototypical Cu (I)–phenanthroline complexes
The excited state properties of transition metal complexes have become a central focus of
research owing to a wide range of possible applications that seek to exploit their …
research owing to a wide range of possible applications that seek to exploit their …