Transition-metal-catalyzed cross-coupling reactions have been well-established as
indispensable tools in modern organic synthesis. One of the major research goals in cross …

The carbon–carbon (C–C) bond cleavage of cyclopropanols is a wide area of research with
much current activity. This review highlights new developments in this area over the past two …

Deoxygenative difunctionalization of carbonyls represents a convenient route to construct
complex molecules considering the readily available aldehyde and ketone compounds. The …

We report a highly stereoselective synthesis of all‐carbon or fluorinated tetrasubstituted
alkenes from diazo reagents and fluorinated enol silyl ethers, using C− F bond as a synthetic …

Asymmetric construction of C–S bonds through transition-metal catalysis is a challenging
subject. By using chiral diene as the ligand, we have developed the first rhodium (I) …

An iron-catalyzed hydroboration of vinylcyclopropane with HBpin is first reported for the
preparation of valuable homoallylic organoboronic esters. The iron catalysts enable efficient …

Reported herein is an exceptional chemoselective ring‐opening/C (sp3)− C (sp3) bond
formation in the copper (I)‐catalyzed reaction of cyclopropanols with diazo esters. The …

A stereoselective, gold-catalyzed, cross-coupling reaction of enynones with diazo
compounds has been developed, affording 2-alkenylfurans in moderate to good yields with …

Efficient copper-catalyzed formal carbene migratory insertion into the olefinic C C bonds of
internal olefins, that is, α-oxo ketene N, S-acetals, has been achieved by means of N …

A cooperative Rh (II)/Pd (0) dual-catalysis strategy that enabled divergent reactions of α-
diazo 1, 3-dicarbonyl compounds with allylic carbonates involving ketene versus carbene …