Porous organic cages

X Yang, Z Ullah, JF Stoddart, CT Yavuz - Chemical Reviews, 2023 - ACS Publications
Porous organic cages (POCs) are a relatively new class of low-density crystalline materials
that have emerged as a versatile platform for investigating molecular recognition, gas …

Zeolites in adsorption processes: State of the art and future prospects

E Pérez-Botella, S Valencia, F Rey - Chemical Reviews, 2022 - ACS Publications
Zeolites have been widely used as catalysts, ion exchangers, and adsorbents since their
industrial breakthrough in the 1950s and continue to be state-of the-art adsorbents in many …

Fluids and electrolytes under confinement in single-digit nanopores

NR Aluru, F Aydin, MZ Bazant, D Blankschtein… - Chemical …, 2023 - ACS Publications
Confined fluids and electrolyte solutions in nanopores exhibit rich and surprising physics
and chemistry that impact the mass transport and energy efficiency in many important …

Purely covalent molecular cages and containers for guest encapsulation

G Montà-González, F Sancenón… - Chemical …, 2022 - ACS Publications
Cage compounds offer unique binding pockets similar to enzyme-binding sites, which can
be customized in terms of size, shape, and functional groups to point toward the cavity and …

Separating water isotopologues using diffusion-regulatory porous materials

Y Su, K Otake, JJ Zheng, S Horike, S Kitagawa, C Gu - Nature, 2022 - nature.com
The discovery of a method to separate isotopologues, molecular entities that differ in only
isotopic composition, is fundamentally and technologically essential but remains …

Artificial channels for confined mass transport at the sub-nanometre scale

J Shen, G Liu, Y Han, W ** - Nature Reviews Materials, 2021 - nature.com
Mass transport at the sub-nanometre scale, including selective transport of gases, liquids
and ions, plays a key role in systems such as catalysis, energy generation and storage …

A smart and responsive crystalline porous organic cage membrane with switchable pore apertures for graded molecular sieving

A He, Z Jiang, Y Wu, H Hussain, J Rawle, ME Briggs… - Nature Materials, 2022 - nature.com
Membranes with high selectivity offer an attractive route to molecular separations, where
technologies such as distillation and chromatography are energy intensive. However, it …

Potential of nonporous adaptive crystals for hydrocarbon separation

M Yan, Y Wang, J Chen, J Zhou - Chemical Society Reviews, 2023 - pubs.rsc.org
Hydrocarbon separation is an important process in the field of petrochemical industry, which
provides a variety of raw materials for industrial production and a strong support for the …

Organic molecular sieve membranes for chemical separations

H Wang, M Wang, X Liang, J Yuan, H Yang… - Chemical Society …, 2021 - pubs.rsc.org
Molecular separations that enable selective transport of target molecules from gas and liquid
molecular mixtures, such as CO2 capture, olefin/paraffin separations, and organic solvent …

Reversible iodine capture by nonporous adaptive crystals of a bipyridine cage

D Luo, Y He, J Tian, JL Sessler… - Journal of the American …, 2021 - ACS Publications
The ability to capture radioactive iodine species is crucial for nuclear accident preparedness
and nuclear waste treatment; however, it remains a challenge. Here we report a new readily …