Progress and prospects in the design of functional atomically-precise Ag (I)-thiolate nanoclusters and their assembly approaches

S Biswas, S Das, Y Negishi - Coordination Chemistry Reviews, 2023 - Elsevier
Atomically-precise noble metal nanoclusters have raised nanomaterials research to new
heights by merit of their distinct structural, optical and electronic properties, which can be …

Surface engineering of atomically precise M (I) nanoclusters: From structural control to room temperature photoluminescence enhancement

S Biswas, AK Das, S Mandal - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Understanding the structural architecture of nanoparticles is essential for
investigating their fundamental properties because these materials have become more …

Advancing electrochemical CO2 reduction with group 11 metal nanoclusters for renewable energy solutions

S Biswas, Y Shingyouchi, M Ogami, M Kamiyama… - EcoEnergy, 2024 - Wiley Online Library
Understanding the intricate relationship between structure and properties is paramount in
distinguishing nanocluster (NC) materials from their counterparts. Despite the progress in …

[Cu 18 H 3 (S-Adm) 12 (PPh 3) 4 Cl 2]: fusion of Platonic and Johnson solids through a Cu (0) center and its photophysical properties

AK Das, S Biswas, VS Wani, AS Nair, B Pathak… - Chemical …, 2022 - pubs.rsc.org
Structural elucidation of atom-precise thiolate-protected copper nanoclusters (Cu NCs)
containing Cu (0) is quite challenging. Here, we report a new adamantane-thiol-protected …

Atom-precise copper nanoclusters based on FCC, BCC, and HCP structures

X Ge, S Zeng, H Deng, BK Teo, C Sun - Coordination Chemistry Reviews, 2024 - Elsevier
In the past decades, coinage nanoclusters (NCs) have attracted much interest for their well-
defined structures, intriguing properties, and various applications. With the development of …

Controlled sequential do** of metal nanocluster

Y Zhou, W Gu, R Wang, W Zhu, Z Hu, W Fei… - Nano …, 2024 - ACS Publications
Atomically precise do** of metal nanoclusters provides excellent opportunities not only for
subtly tailoring their properties but also for in-depth understanding of composition (structure) …

Nested Keplerian architecture of [Cu 58 H 20 (SPr) 36 (PPh 3) 8] 2+ nanoclusters

S Biswas, S Hossian, T Kosaka, J Sakai… - Chemical …, 2023 - pubs.rsc.org
This article explores the challenges in synthesizing highly symmetric Cu (I)–thiolate
nanoclusters and reports a nested Keplerian architecture of [Cu58H20 (SPr) 36 (PPh3) 8] …

An atomically precise silver nanocluster for artificial light-harvesting system through supramolecular functionalization

AK Das, S Biswas, SS Manna, B Pathak, S Mandal - Chemical Science, 2022 - pubs.rsc.org
Designing an artificial light-harvesting system (LHS) with high energy transfer efficiency has
been a challenging task. Herein, we report an atom-precise silver nanocluster (Ag NC) as a …

Two-Dimensional Silver-Chalcogenolate-Based Cluster-Assembled Material: A p-type Semiconductor

AK Das, S Biswas, A Kayal, AC Reber, S Bhandary… - Nano Letters, 2023 - ACS Publications
We have synthesized and characterized a new two-dimensional honeycomb architecture
resembling a single-layer of atomically precise silver cluster-assembled material …

In Situ Depletion-Guided Engineering of Nanoshell-like Gold Nanocluster Assemblies with Enhanced Peroxidase-like Nanozyme Activity

D Bera, A Mukhopadhyay, Nonappa… - The journal of physical …, 2023 - ACS Publications
Functional superstructures constructed from metal nanoclusters (MNCs) hold great promise
in providing highly tunable photoluminescence (PL), catalytic activity, photothermal stability …