Visible light‐mediated direct decarboxylation of carboxylic acids with an acridine
photocatalyst is a convenient and powerful method to generate carbon‐centered radicals in …

Organocatalysis has evolved into an effective complement to metal‐or enzyme‐based
catalysis in polymerization, polymer functionalization, and depolymerization. The ease of …

In situ heterogeneous olefin polymerization has attracted much attention for the synthesis of
polyolefin composites. However, the complicated syntheses of specially designed catalysts …

Branched polyolefin microstructures resulting from so‐called “chain walking” are a
fascinating feature of late transition metal catalysts; however, to date it has not been …

The practical synthesis of polar‐functionalized polyolefins using transition‐metal‐catalyzed
copolymerization of olefins with polar monomers is a challenge; the use of heterogeneous …

In this contribution, we install an azobenzene functionality in olefin polymerization catalysts
and use light to modulate their properties via photoinduced trans–cis isomerization of the …

The synthesis of polar functionalized polyolefin (PFP) offers improvement in mixing
properties, polymer surface, and rheological properties with the potential of upgraded …

The incorporation of comonomers during ethylene polymerization can efficiently modulate
important material properties of the polyolefins. Utilizing bioresourced comonomers for the …

An effective shielding of both apical positions of a neutral NiII active site is achieved by
dibenzosuberyl groups, both attached via the same donors' N‐aryl group in a Cs‐type …

The introduction of m‐xylyl substituents to α‐diimine PdII catalyst promotes living ethylene
polymerization at room temperature and low pressure to yield high molecular weight …