Adiabatic connection interaction strength interpolation method made accurate for the uniform electron gas

LA Constantin, S Jana, S Śmiga… - The Journal of Chemical …, 2023 - pubs.aip.org
The adiabatic connection interaction strength interpolation (ISI)-like method provides a high-
level expression for the correlation energy, being, in principle, exact not only in the weak …

Chemical Potentials and the One-Electron Hamiltonian of the Second-Order Perturbation Theory from the Functional Derivative Approach

J Li, W Yang - The Journal of Physical Chemistry A, 2024 - ACS Publications
We develop a functional derivative approach to calculate the chemical potentials of second-
order perturbation theory (MP2). In the functional derivative approach, the correlation part of …

Reaching high accuracy for energetic properties at second-order perturbation cost by merging self-consistency and spin-opposite scaling

NT Tran, HT Nguyen, LN Tran - The Journal of Physical Chemistry …, 2024 - ACS Publications
Quantum chemical methods dealing with challenging systems while retaining low
computational costs have attracted attention. In particular, many efforts have been devoted …

Møller–Plesset Adiabatic Connection at Large Coupling Strengths for Open-Shell Systems

KJ Daas, E Klute, M Seidl… - The Journal of Physical …, 2024 - ACS Publications
We study the adiabatic connection that has as weak-coupling expansion the Møller-Plesset
perturbation series, generalizing to the open-shell case previous closed-shell results for the …

Towards adiabatic-connection interpolation model with broader applicability

LA Constantin, S Śmiga, F Della Sala - Physical Review B, 2024 - APS
The adiabatic connection integrand interpolation (ACII) method represents a general path
for calculating correlation energies in electronic systems within the density functional theory …

Real-space machine learning of correlation density functionals

E Polak, H Zhao, S Vuckovic - 2024 - chemrxiv.org
Machine learning (ML) has started to play a pivotal role in extending the reach of quantum
chemistry methods for both molecules and materials. However, in density functional theory …

Electronic orbital responses of extended systems to static, homogeneous, electromagnetic fields

M Springborg, B Kirtman - 2024 - books.rsc.org
We discuss theoretical methods with which the effects of static, homogenous,
electromagnetic fields can be determined for systems that are extended and in the ultimate …

The adiabatic connection formalism in DFT–theory and practice

E Polak, KJ Daas, S Vuckovic - 2024 - books.rsc.org
The adiabatic connection formalism yielding an exact expression to exchange–correlation
functional, has been instrumental in building DFT approximations. Here, we derive and …

The Strong Interaction Limit of the Møller-Plesset Adiabatic Connection: From Theory to Applications

KJ Daas - 2024 - research.vu.nl
All the information needed to describe chemical reactions can be obtained by solving the
time dependent Schrödinger equation. However, this is only viable for the smallest of …