Metal–organic frameworks and derived materials as photocatalysts for water splitting and carbon dioxide reduction

J Chen, R Abazari, KA Adegoke, NW Maxakato… - Coordination Chemistry …, 2022 - Elsevier
One of the currently proposed solutions for finding alternatives to fossil fuels and combating
environmental pollution concerns the development of advanced materials for clean and …

Metal–organic frameworks as electrocatalysts

Y Peng, S Sanati, A Morsali… - Angewandte Chemie …, 2023 - Wiley Online Library
Transition metal complexes are well‐known homogeneous electrocatalysts. In this regard,
metal–organic frameworks (MOFs) can be considered as an ensemble of transition metal …

Dislocated Bilayer MOF Enables High‐Selectivity Photocatalytic Reduction of CO2 to CO

J Liang, H Yu, J Shi, B Li, L Wu, M Wang - Advanced materials, 2023 - Wiley Online Library
The highly selective photoreduction of CO2 into valuable small‐molecule chemical
feedstocks such as CO is an effective strategy for addressing the energy crisis and …

[PDF][PDF] Porphyrin-based framework materials for energy conversion

J Gu, Y Peng, T Zhou, J Ma, H Pang… - Nano Res …, 2022 - researchgate.net
With the increasing demand for fuel causing serious environmental pollution, it is urgent to
develop new and environmentally friendly energy conversion devices. These energy …

In situ construction of metal–organic frameworks as smart channels for the effective electrocatalytic reduction of nitrate at ultralow concentrations to ammonia

Z Wang, S Liu, M Wang, L Zhang, Y Jiang, T Qian… - ACS …, 2023 - ACS Publications
Electrochemical conversion of nitrate, a widespread water pollutant, into high-value-added
ammonia is a renewable and delocalized route to restore the globally perturbed nitrogen …

Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide

Z Liang, HY Wang, H Zheng, W Zhang… - Chemical Society …, 2021 - pubs.rsc.org
Porphyrin-based frameworks, as specific kinds of metal–organic frameworks (MOFs) and
covalent organic frameworks (COFs), have been widely used in energy-related conversion …

Atomic-level design of metalloenzyme-like active pockets in metal–organic frameworks for bioinspired catalysis

W Xu, Y Wu, W Gu, D Du, Y Lin, C Zhu - Chemical Society Reviews, 2024 - pubs.rsc.org
Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …

Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

NF Suremann, BD McCarthy, W Gschwind… - Chemical …, 2023 - ACS Publications
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …

[HTML][HTML] Porous fixed-bed photoreactor for boosting C–C coupling in photocatalytic CO2 reduction

S Bai, H Qiu, M Song, G He, F Wang, Y Liu, L Guo - eScience, 2022 - Elsevier
Solar-driven CO 2 conversion to chemical fuels in an aqueous solution is restricted not only
by photocatalysts but also by mass transfer. Here, a regulatable three-phase interface on a …

Strategies for enhancing the catalytic activity and electronic conductivity of MOFs-based electrocatalysts

P Zhou, J Lv, X Huang, Y Lu, G Wang - Coordination Chemistry Reviews, 2023 - Elsevier
Electrocatalysis plays a key role in the modern energy storage and conversion since the
introduction of state-of-the-art electrocatalysts contributes to reducing the energy …