Chemistry of azoimidazoles: synthesis, spectral characterization, electrochemical studies, and X-ray crystal structures of isomeric dichloro bis [1-alkyl-2-(arylazo) …
Several new ligands, azoimidazoles belonging to the class 1-methyl-2-(arylazo) imidazoles
(L1 (3)) and 1-benzyl-2-(arylazo) imidazoles (L2 (4))(R= H (a), Me (b), OMe (c), Cl (d), NO2 …
(L1 (3)) and 1-benzyl-2-(arylazo) imidazoles (L2 (4))(R= H (a), Me (b), OMe (c), Cl (d), NO2 …
Exclusively ligand-mediated catalytic dehydrogenation of alcohols
Design of an efficient new catalyst that can mimic the enzymatic pathway for catalytic
dehydrogenation of liquid fuels like alcohols is described in this report. The catalyst is a …
dehydrogenation of liquid fuels like alcohols is described in this report. The catalyst is a …
Radical versus nonradical states of azobis (benzothiazole) as a function of ancillary ligands on selective ruthenium platforms
The paper deals with the electronic impact of ancillary ligands on the varying redox features
of azobis (benzothiazole)(abbt) in the newly introduced mononuclear ruthenium complexes …
of azobis (benzothiazole)(abbt) in the newly introduced mononuclear ruthenium complexes …
Noninnocence of indigo: dehydroindigo anions as bridging electron-donor ligands in diruthenium complexes
Complexes of singly or doubly deprotonated indigo (H2Ind) with one or two [Ru (pap) 2] 2+
fragments (pap= 2-phenylazopyridine) have been characterized experimentally [molecular …
fragments (pap= 2-phenylazopyridine) have been characterized experimentally [molecular …
Introducing a new azoaromatic pincer ligand. Isolation and characterization of redox events in its ferrous complexes
The isolation and complete characterization of a new bis-azoaromatic ligand, 2, 6-bis
(phenylazo) pyridine (L), are described, and its coordination to iron (II) is reported. A pseudo …
(phenylazo) pyridine (L), are described, and its coordination to iron (II) is reported. A pseudo …
Isolation and structure of the first azo anion radical complexes of ruthenium
The anaerobic reaction of 1 (X= H, Cl) with 2 in heptane affords the green paramagnetic (S=
1/2) and EPR-active (g= 2.00) title complexes 3a (X= H) and 3b (X= Cl), which furnish the …
1/2) and EPR-active (g= 2.00) title complexes 3a (X= H) and 3b (X= Cl), which furnish the …
Electrochromic platinum (II) complexes derived from azobenzene and zwitterionic quinonoid ligands: electronic and geometric structures
N Deibel, S Hohloch, MG Sommer… - …, 2013 - ACS Publications
The ligands azobenzene (az) and the zwitterionic 4-(isopropylamino)-6-(isopropyliminio)-3-
oxocyclohexa-1, 4-dien-1-olate (Q) were used to synthesize the mononuclear complex [(QH) …
oxocyclohexa-1, 4-dien-1-olate (Q) were used to synthesize the mononuclear complex [(QH) …
Sensitive Valence Structures of [(pap)2Ru(Q)]n (n = +2, +1, 0, −1, −2) with Two Different Redox Noninnocent Ligands, Q = 3,5-Di-tert-butyl-N-aryl-1,2 …
The complexes [(pap) 2Ru (Q)] ClO4,[1] ClO4−[4] ClO4, with two different redox noninnocent
ligands, Q= 3, 5-di-tert-butyl-N-aryl-1, 2-benzoquinonemonoimine (-aryl= m-(Cl) 2C6H3 (1+) …
ligands, Q= 3, 5-di-tert-butyl-N-aryl-1, 2-benzoquinonemonoimine (-aryl= m-(Cl) 2C6H3 (1+) …
Bidirectional noninnocence of hinge-like deprotonated bis-lawsone on selective ruthenium platform: a function of varying ancillary ligands
The present work aimed to obtain discrete heavier metal complexes of unperturbed
deprotonated bis-lawsone (hinge-like H2L= 2, 2′-bis (3-hydroxy-1, 4-napthoquinone). This …
deprotonated bis-lawsone (hinge-like H2L= 2, 2′-bis (3-hydroxy-1, 4-napthoquinone). This …
Near‐IR Absorbing Ruthenium Complexes of Non‐Innocent 6,12‐Di(pyridin‐2‐yl)indolo[3,2‐b]carbazole: Variation as a Function of Co‐Ligands
This article deals with the hitherto unexplored metal complexes of deprotonated 6, 12‐di
(pyridin‐2‐yl)‐5, 11‐dihydroindolo [3, 2‐b] carbazole (H2L). The synthesis and structural …
(pyridin‐2‐yl)‐5, 11‐dihydroindolo [3, 2‐b] carbazole (H2L). The synthesis and structural …