Combustion chemistry in the twenty-first century: Develo** theory-informed chemical kinetics models
Over the last 20 to 25 years theoretical chemistry (particularly theoretical chemical kinetics)
has played an increasingly important role in develo** chemical kinetics models for …
has played an increasingly important role in develo** chemical kinetics models for …
[HTML][HTML] Reactive oxygen species: The dual role in physiological and pathological conditions of the human body
Reactive oxygen species (ROS) are well-known for playing a dual role as destructive and
constructive species. Indeed, ROS are engaged in many redox-governing activities of the …
constructive species. Indeed, ROS are engaged in many redox-governing activities of the …
Synthesis of cyclobutane-fused angular tetracyclic spiroindolines via visible-light-promoted intramolecular dearomatization of indole derivatives
M Zhu, C Zheng, X Zhang, SL You - Journal of the American …, 2019 - ACS Publications
An intramolecular dearomatization of indole derivatives based on visible-light-promoted [2+
2] cycloaddition was achieved via energy transfer mechanism. The highly strained …
2] cycloaddition was achieved via energy transfer mechanism. The highly strained …
C H Bond Activation in Transition Metal Species from a Computational Perspective
Alkanes constitute the cheapest and most abundant feedstock for organic chemicals.
However, the redistribution of CsC and CsH bonds in hydrocarbons into more sophisticated …
However, the redistribution of CsC and CsH bonds in hydrocarbons into more sophisticated …
Nine-membered benzofuran-fused heterocycles: enantioselective synthesis by Pd-catalysis and rearrangement via transannular bond formation
The first enantioselective formal [5+ 4] cycloaddition is realized under palladium catalysis to
deliver benzofuran-fused nine-membered rings. These medium-sized heterocycles and …
deliver benzofuran-fused nine-membered rings. These medium-sized heterocycles and …
Direct stereospecific synthesis of unprotected NH and N-Me aziridines from olefins
Despite the prevalence of the NH aziridine motif in bioactive natural products and the clear
advantages of this unprotected parent structure over N-protected derivatives as a synthetic …
advantages of this unprotected parent structure over N-protected derivatives as a synthetic …
Diradical generation via relayed proton-coupled electron transfer
Diradical generation followed by radical–radical cross-coupling is a powerful synthetic tool,
but its detailed mechanism has yet to be established. Herein, we proposed and confirmed a …
but its detailed mechanism has yet to be established. Herein, we proposed and confirmed a …
N-Heterocyclic carbene-based C-centered Au(I)-Ag(I) clusters with intense phosphorescence and organelle-selective translocation in cells
Photoluminescent gold clusters are functionally variable chemical modules by ligand
design. Chemical modification of protective ligands and introduction of different metals into …
design. Chemical modification of protective ligands and introduction of different metals into …
Selective activation of alkanes by gas-phase metal ions
J Roithova, D Schroder - Chemical reviews, 2010 - ACS Publications
The importance of the selective activation of alkanes for science and technology in the
forthcoming decades does not need to be explicitly pointed out in this thematic issue of …
forthcoming decades does not need to be explicitly pointed out in this thematic issue of …
Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation
Compared with the popularity of various C-centred radicals, the N-centred radicals remain
largely unexplored in catalytic radical cascade reactions because of a lack of convenient …
largely unexplored in catalytic radical cascade reactions because of a lack of convenient …