Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …
and selectivity. However, the structural complexity and vulnerability hamper the application …
Stable metal–organic frameworks: design, synthesis, and applications
Metal–organic frameworks (MOFs) are an emerging class of porous materials with potential
applications in gas storage, separations, catalysis, and chemical sensing. Despite numerous …
applications in gas storage, separations, catalysis, and chemical sensing. Despite numerous …
A historical overview of the activation and porosity of metal–organic frameworks
Since the first reports of metal–organic frameworks (MOFs), this unique class of crystalline,
porous materials has garnered increasing attention in a wide variety of applications such as …
porous materials has garnered increasing attention in a wide variety of applications such as …
From fundamentals to applications: a toolbox for robust and multifunctional MOF materials
In recent years, metal–organic frameworks (MOFs) have been regarded as one of the most
important classes of materials. The combination of various metal clusters and ligands …
important classes of materials. The combination of various metal clusters and ligands …
Zr-based metal–organic frameworks: design, synthesis, structure, and applications
Among the large family of metal–organic frameworks (MOFs), Zr-based MOFs, which exhibit
rich structure types, outstanding stability, intriguing properties and functions, are foreseen as …
rich structure types, outstanding stability, intriguing properties and functions, are foreseen as …
Post‐synthetic modification of metal–organic frameworks toward applications
Post‐synthetic modification (PSM) of metal–organic framework (MOF) compounds is a useful
technique for preparing new MOFs that can exhibit or enhance many of the properties of the …
technique for preparing new MOFs that can exhibit or enhance many of the properties of the …
Defect engineering: tuning the porosity and composition of the metal–organic framework UiO-66 via modulated synthesis
Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when
synthesized in the presence of monocarboxylic acid modulators under the most commonly …
synthesized in the presence of monocarboxylic acid modulators under the most commonly …
25 years of reticular chemistry
At its core, reticular chemistry has translated the precision and expertise of organic and
inorganic synthesis to the solid state. While initial excitement over metal–organic …
inorganic synthesis to the solid state. While initial excitement over metal–organic …
A reticular chemistry guide for the design of periodic solids
Reticular chemistry—the linking of well-defined molecular building blocks by strong bonds
into crystalline extended frameworks—has enabled the synthesis of diverse metal–organic …
into crystalline extended frameworks—has enabled the synthesis of diverse metal–organic …
Secondary building units as the turning point in the development of the reticular chemistry of MOFs
The secondary building unit (SBU) approach was a turning point in the discovery of
permanently porous metal-organic frameworks (MOFs) and in launching the field of reticular …
permanently porous metal-organic frameworks (MOFs) and in launching the field of reticular …