Transition metal complexes are of increasing interest as photosensitizers in photodynamic
therapy (PDT) and, more recently, for photochemotherapy (PCT). In recent years, Ru (II) …

Ribonucleotide reductases (RNRs) catalyze the conversion of nucleotides to
deoxynucleotides in all organisms (eq 1). 1-3 These enzymes play an essential role in DNA …

Rapid photoinduced electron transfer is demonstrated over a distance of greater than 40
angstroms between metallointercalators that are tethered to the 5′ termini of a 15-base pair …

This book covers material that could be included in a one-quarter or one-semester course in
bioinorganic chemistry for graduate students and advanced undergraduate students in …

THE possibility has been considered for almost forty years that the DNA double helix, which
contains a π-stacked array of heterocyclic base pairs, could be a suitable medium for the …

1.74 X 10s M" 1 yield 8.6±0.2 mM base pairs. Cyclic voltammetric peak separations indicate
that heterogeneous electron transfer is slower at DNA-modified electrodes than at …

Gold surfaces have been derivatized with 15-base-pair double-stranded DNA
oligonucleotides containing a pendant 5 'hexanethiol linker. The electrochemistry of …

The invention relates to compositions and methods useful in the acceleration of binding of
target analytes to capture ligands on surfaces. Detection proceeds through the use of an …

Ultrafast emission and absorption spectroscopies were used to measure the kinetics of DNA-
mediated electron transfer reactions between metal complexes intercalated into DNA. In the …

Whether the DNA base pair stack might serve as a medium for efficient, long‐range charge
transfer has been debated almost since the first proposal of the double‐helical structure of …