In the early seventies one of us1 was involved in the development of the heterogeneous Ti
(IV)/SiO2 catalyst which forms the basis of the Shell process for the epoxidation of propylene …

This review article aims to cover the state-of-the-art of titanosilicate catalysts for selective
oxidations developed within past seven years. Many elaborated materials (eg, layered and …

Propene oxide is a very important chemical whose production technology has changed a lot
during the last 30 years. Nowadays, the most promising technology is the HPPO process in …

Zeolites containing Sn, Ti, Zr, Hf, Nb, or Ta heteroatoms are versatile catalysts for the
activation and conversion of oxygenated molecules owing to the unique Lewis acid …

This contribution relates a new application of Ti-containing molecular sieves as catalysts for
the oxidation of aromatic sulfur compounds with hydrogen peroxide under mild conditions …

Recent reports on the organic structure-directing agent (OSDA)-free synthesis of some
zeolites with the aid of seed crystals have opened a new way to the robust and …

Ti-silicates activate H 2 O 2 to form Ti-hydroperoxo and Ti-peroxo intermediates that can
react with alkenes to form epoxide products. Comparisons of kinetics for 1-octene …

A comparative study concerning the use of Ti-containing molecular sieves with MFI (TS-1),
BEA (Ti-beta) and MCM-41 (TiMCM-41) topologies for the styrene oxidation in liquid phase …

Solvent molecules alter the free energies of liquid phase species and adsorbed
intermediates during catalytic reactions, thereby impacting rates and selectivities. Here, we …

A new titanosilicate, named Del-Ti-MWW, has been prepared by delaminating the lamellar
precursor of Ti-MWW, which is postsynthesized from highly deboronated MWW zeolite with …