In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-
group elements. Enantioenriched helicenic derivatives containing main-group elements B …

Atropisomers are molecules whose stereogenicity arises from restricted rotation about a
single bond. They are of current importance because of their applications in catalysis …

Conspectus Asymmetric synthesis constitutes a key technology for the preparation of
enantiomerically pure compounds as well as for the selective control of individual …

A catalytic enantioselective nucleophilic aromatic substitution reaction which yields axially
chiral biaryl derivatives in excellent yields with er values of up to 97: 3 has been developed …

The asymmetric synthesis of a range of axially chiral 2-arylpyridines by a cobalt-catalyzed
[2+ 2+ 2] cycloaddition reaction is described. The use of a planar chiral (1 …

The chapter “Atropisomerism and axial chirality in heteroaromatic compounds” provides a
summary of the present knowledge of this important topic. The structure of the chapter is: first …

Atropisomeric N-chloroamides were efficiently accessed by electrophilic halogenation of
ortho-substituted secondary anilides. The stereodynamics of atropisomerism in these novel …

The software program DCXplorer is introduced to directly access interconversion rate
constants in dynamic chromatography and electrophoresis. The program utilizes the unified …

This review continues a general presentation of the principles of stereochemistry with
special reference to medicinal compounds. Here, we discuss further stereogenic elements …

A series of different unsymmetrically substituted naphthyl-based diynes were synthesized.
These substrates formed the foundation for the assembly of novel biaryls containing pyridine …