Emerging trends in spin crossover (SCO) based functional materials and devices
The design and synthesis of functional molecules with controllable properties are at the
forefront of modern materials chemistry research due to their diverse applicability, especially …
forefront of modern materials chemistry research due to their diverse applicability, especially …
Vapochromic effect in switchable molecular-based spin crossover compounds
E Resines-Urien, E Fernandez-Bartolome… - Chemical Society …, 2023 - pubs.rsc.org
Coordination complexes based on transition metal ions displaying [Ar] 3d4–3d7 electronic
configurations can undergo the likely most spectacular switchable phenomena found in …
configurations can undergo the likely most spectacular switchable phenomena found in …
Solution Spin Crossover Versus Speciation Effects: A Cautionary Tale
S Sundaresan, S Brooker - Inorganic Chemistry, 2023 - ACS Publications
Two acyclic tetradentate Schiff base ligands, HLX–OH (X= H and Br), were synthesised by 2:
1 condensation of either 2-pyridinecarboxaldehyde or 5-bromo-2-pyridinecarboxaldehyde …
1 condensation of either 2-pyridinecarboxaldehyde or 5-bromo-2-pyridinecarboxaldehyde …
Zeolites for theranostic applications
Theranostic platforms bring about a revolution in disease management. During recent years,
theranostic nanoparticles have been utilized for imaging and therapy simultaneously …
theranostic nanoparticles have been utilized for imaging and therapy simultaneously …
Ni-centered coordination-induced spin-state switching triggered by electrical stimulation
S Al Shehimy, O Baydoun… - Journal of the …, 2022 - ACS Publications
We herein report the synthesis and magnetic properties of a Ni (II)-porphyrin tethered to an
imidazole ligand through a flexible electron-responsive mechanical hinge. The latter is …
imidazole ligand through a flexible electron-responsive mechanical hinge. The latter is …
pH-Switching of the luminescent, redox, and magnetic properties in a spin crossover cobalt (ii) molecular nanomagnet
The ability of mononuclear first-row transition metal complexes as dynamic molecular
systems to perform selective functions under the control of an external stimulus that …
systems to perform selective functions under the control of an external stimulus that …
Confinement inside MOFs Enables Guest-Modulated Spin Crossover of Otherwise Low-Spin Coordination Cages
SL Yang, X Zhang, Q Wang, C Wu, H Liu, D Jiang… - JACS Au, 2023 - ACS Publications
Confinement of discrete coordination cages within nanoporous lattices is an intriguing
strategy to gain unusual properties and functions. We demonstrate here that the confinement …
strategy to gain unusual properties and functions. We demonstrate here that the confinement …
Charge transfer-triggered reversible spin-state switching
YH Luo, C Xue, SX Zhang, J Zhao, XT **… - Journal of Materials …, 2024 - pubs.rsc.org
Triggering the spin-state switching (SSS) in solutions at room temperature (RT) has attracted
attention in the field of molecular switches. Herein, we report the preparation and switching …
attention in the field of molecular switches. Herein, we report the preparation and switching …
Spin State Chemistry: Modulation of Ligand pKa by Spin State Switching in a [2×2] Iron(II) Grid-Type Complex
The iron (II)[2× 2] grid complex Fe-8H has been synthesized and characterized. It undergoes
spin-crossover (SCO) upon deprotonation of the hydrazine-based terpyridine-like ligand …
spin-crossover (SCO) upon deprotonation of the hydrazine-based terpyridine-like ligand …
Stimuli-responsive magnetic materials: impact of spin and electronic modulation
Addressing molecular bistability as a function of external stimuli, especially in spin-crossover
(SCO) and metal-to-metal electron transfer (MMET) systems, has seen a surge of interest in …
(SCO) and metal-to-metal electron transfer (MMET) systems, has seen a surge of interest in …