Emerging trends in spin crossover (SCO) based functional materials and devices

KS Kumar, M Ruben - Coordination Chemistry Reviews, 2017 - Elsevier
The design and synthesis of functional molecules with controllable properties are at the
forefront of modern materials chemistry research due to their diverse applicability, especially …

Vapochromic effect in switchable molecular-based spin crossover compounds

E Resines-Urien, E Fernandez-Bartolome… - Chemical Society …, 2023 - pubs.rsc.org
Coordination complexes based on transition metal ions displaying [Ar] 3d4–3d7 electronic
configurations can undergo the likely most spectacular switchable phenomena found in …

Solution Spin Crossover Versus Speciation Effects: A Cautionary Tale

S Sundaresan, S Brooker - Inorganic Chemistry, 2023 - ACS Publications
Two acyclic tetradentate Schiff base ligands, HLX–OH (X= H and Br), were synthesised by 2:
1 condensation of either 2-pyridinecarboxaldehyde or 5-bromo-2-pyridinecarboxaldehyde …

Zeolites for theranostic applications

MK Yazdi, P Zarrintaj, H Hosseiniamoli… - Journal of Materials …, 2020 - pubs.rsc.org
Theranostic platforms bring about a revolution in disease management. During recent years,
theranostic nanoparticles have been utilized for imaging and therapy simultaneously …

Ni-centered coordination-induced spin-state switching triggered by electrical stimulation

S Al Shehimy, O Baydoun… - Journal of the …, 2022 - ACS Publications
We herein report the synthesis and magnetic properties of a Ni (II)-porphyrin tethered to an
imidazole ligand through a flexible electron-responsive mechanical hinge. The latter is …

pH-Switching of the luminescent, redox, and magnetic properties in a spin crossover cobalt (ii) molecular nanomagnet

R Rabelo, L Toma, N Moliner, M Julve, F Lloret… - Chemical …, 2023 - pubs.rsc.org
The ability of mononuclear first-row transition metal complexes as dynamic molecular
systems to perform selective functions under the control of an external stimulus that …

Confinement inside MOFs Enables Guest-Modulated Spin Crossover of Otherwise Low-Spin Coordination Cages

SL Yang, X Zhang, Q Wang, C Wu, H Liu, D Jiang… - JACS Au, 2023 - ACS Publications
Confinement of discrete coordination cages within nanoporous lattices is an intriguing
strategy to gain unusual properties and functions. We demonstrate here that the confinement …

Charge transfer-triggered reversible spin-state switching

YH Luo, C Xue, SX Zhang, J Zhao, XT **… - Journal of Materials …, 2024 - pubs.rsc.org
Triggering the spin-state switching (SSS) in solutions at room temperature (RT) has attracted
attention in the field of molecular switches. Herein, we report the preparation and switching …

Spin State Chemistry: Modulation of Ligand pKa by Spin State Switching in a [2×2] Iron(II) Grid-Type Complex

S Dhers, A Mondal, D Aguilà, J Ramirez… - Journal of the …, 2018 - ACS Publications
The iron (II)[2× 2] grid complex Fe-8H has been synthesized and characterized. It undergoes
spin-crossover (SCO) upon deprotonation of the hydrazine-based terpyridine-like ligand …

Stimuli-responsive magnetic materials: impact of spin and electronic modulation

K Kaushik, S Mehta, M Das, S Ghosh… - Chemical …, 2023 - pubs.rsc.org
Addressing molecular bistability as a function of external stimuli, especially in spin-crossover
(SCO) and metal-to-metal electron transfer (MMET) systems, has seen a surge of interest in …