The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

This review provides a comprehensive view of the application of first-row transition metals in
asymmetric hydrogenation and asymmetric transfer hydrogenation. The catalytic behavior of …

Conspectus The hydrogenation of alkenes is one of the most impactful reactions catalyzed
by homogeneous transition metal complexes finding application in the pharmaceutical …

The development of novel and efficient earth-abundant metal catalysts as inexpensive and
sustainable alternatives to noble-metal catalysts is a rapidly expanding and evolving field of …

Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐or
alkenyl‐metal reagents, which have a wide range of applications in organic transformations …

Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an
impact on various aspects of the coordination, organometallic, and catalytic chemistry of the …

Conspectus Comprising periodically repeating inorganic nodes and organic linkers, metal–
organic frameworks (MOFs) represent a novel class of porous molecular solids with well …

A thorough understanding of the pharmacokinetic and pharmacodynamic properties of a
drug in animal models is a critical component of drug discovery and development,,,,,. Such …

Herein, we report a novel cobalt-catalyzed stereodivergent transfer hydrogenation of
alkynes to Z-and E-alkenes. Effective selectivity control is achieved based on a rational …