Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …

Low-valent early transition metals are often intrinsically highly reactive as a result of their
strong propensity toward oxidation to more stable high-valent states. Harnessing these …

The synthesis of NH-free pyrroles via Pd-catalyzed annulation of enaminones and alkenes
is reported. With the catalysis of Pd (II), the activation of triple C (sp2)–H bonds, including …

Global shellfishery waste generation is from 6 to 8 million metric tons annually. Chitin, as a
major component in crustacean shells, is the second most abundant biopolymer on Earth …

Separation science plays a critical role in maintaining our standard of living and quality of
life. Many industrial processes and general necessities such as chemicals, medicines, clean …

The utility of carbazole in photo-, electro-, and medicinal applications has ensured its
widespread use also as the backbone in tridentate pincer ligands. In this review, the aim is …

Trimethylsilyl (TMS)‐protected alkynes served as selective alkyne cross‐coupling partners
in titanium‐catalyzed [2+ 2+ 1] pyrrole synthesis. Reactions of TMS‐protected alkynes with …

Pyrazoles are an important class of heterocycles found in a wide range of bioactive
compounds and pharmaceuticals. Pyrazole synthesis often requires hydrazine or related …

Conspectus Titanium is an attractive metal for catalytic reaction development: it is earth-
abundant, inexpensive, and generally nontoxic. However—like most early transition metals …

A Pd-catalyzed decarboxylative approach for the modular synthesis of highly functionalized
pyrroles is presented. This protocol utilizes readily available cyclic carbonates and amines …