Restriction of intramolecular motion (RIM): investigating AIE mechanism from experimental and theoretical studies

J Zhang, H Zhang, JWY Lam, BZ Tang - Chemical Research in Chinese …, 2021 - Springer
Mechanistic studies promote scientific development from phenomena to theories.
Aggregation-induced emission (AIE), as an unusual photophysical phenomenon, builds the …

Azo group (s) in selected macrocyclic compounds

E Wagner-Wysiecka, N Łukasik, JF Biernat… - Journal of Inclusion …, 2018 - Springer
Azobenzene derivatives due to their photo-and electroactive properties are an important
group of compounds finding applications in diverse fields. Due to the possibility of …

Photon energy storage in strained cyclic hydrazones: emerging molecular solar thermal energy storage compounds

Q Qiu, S Yang, MA Gerkman, H Fu… - Journal of the …, 2022 - ACS Publications
The generally small Gibbs free energy difference between the Z and E isomers of hydrazone
photoswitches has so far precluded their use in photon energy storing applications. Here …

[BOK][B] Photochemistry of organic compounds: from concepts to practice

P Klán, J Wirz - 2009 - books.google.com
Photochemistry of Organic Compounds: From Concepts to Practice provides a hands-on
guide demonstrating the underlying principles of photochemistry and, by reference to a …

Highly Efficient Reversible Z−E Photoisomerization of a Bridged Azobenzene with Visible Light through Resolved S1(nπ*) Absorption Bands

R Siewertsen, H Neumann… - Journal of the …, 2009 - ACS Publications
The reversible Z− E photoswitching properties of the (Z) and (E) isomers of the severely
constrained bridged azobenzene derivative 5, 6-dihydrodibenzo [c, g][1, 2] diazocine (1) …

Photoinduced isothermal phase transitions of liquid-crystalline macrocyclic azobenzenes

Y Norikane, Y Hirai, M Yoshida - Chemical Communications, 2011 - pubs.rsc.org
Liquid-crystalline macrocyclic compounds, tethered by two or three azobenzenes bearing
alkoxy side chains, exhibit isothermal phase transitions from liquid-crystal to isotropic as well …

Building strain with large macrocycles and using it to tune the thermal half-lives of hydrazone photochromes

Q Li, H Qian, B Shao, RP Hughes… - Journal of the American …, 2018 - ACS Publications
Strain has been used as a tool to modulate the reactivity (eg, mechanochemistry) and
thermal isomerization kinetics of photochromic compounds. Macrocyclization is used to build …

Stepwise two-photon absorption processes utilizing photochromic reactions

Y Kobayashi, K Mutoh, J Abe - Journal of Photochemistry and Photobiology …, 2018 - Elsevier
Stepwise two-photon absorption (2PA) is one of the nonlinear photoresponses where two
photons are sequentially absorbed to proceed a photophysical or photochemical reaction …

Impact of crystallites in nematic elastomers on dynamic mechanical properties and adhesion

T Ohzono, H Minamikawa, E Koyama… - Macromolecules, 2021 - ACS Publications
Crystallite formation in cross-linked polymeric networks can generally affect their mechanical
properties, resulting in a higher modulus and strength than those expected from pure …

Oligoazobenzenophanes—synthesis, photochemistry and properties

R Reuter, HA Wegner - Chemical Communications, 2011 - pubs.rsc.org
The possibility to modulate molecules reversibly by light has been fascinating chemists early
on. One of the most powerful photochromic classes of compounds are azobenzenes, which …