C− H activation is an attractive methodology to increase molecular complexity without
requiring substrate prefunctionalization. In contrast to well‐established cross‐coupling …

What factors will play a role in the decision process when looking at the reasons for certain
reactions being adopted for large-scale industrial applications? An examination reveals that …

The functionalization of C–H bonds enables the modification of complex molecules, often
with the intention of forming compound libraries. The borylation of aryl C–H bonds is a …

Despite coordination environment of catalytic metal sites has been recognized to be of great
importance in single‐atom catalysts (SACs), a significant challenge remains in the …

We report a class of isolable bis‐cyclometallated iridium precatalysts (ImIr) and their use in
regioselective ortho− C− H borylation of aromatic, heteroaromatic, acrylic, and aliphatic …

Carbon-hydrogen bond activations and their subsequent functionalisation have long been
an important target in chemistry because C‐H bonds are ubiquitous throughout nature …

This report details the development of an efficient process to prepare methyl 4, 5, 6-
trichloropicolinate using Ir-catalyzed C–H borylation followed by CuCl2-mediated …

Abstract Die C− H‐Aktivierung ist eine attraktive Methode zur Steigerung der molekularen
Komplexität, ohne Vorfunktionalisierung des Substrats. Im Gegensatz zu den etablierten …

This work outlines the synthesis of several new η 5-indenyl rhodium (I) N-heterocyclic
carbene (NHC) cyclooctene (COE) complexes. The effect of changing the NHC from SIDipp …